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AlkylFluor™
(CAS RN:2043361-32-4 Product Number:B5480)

Structure

AlkylFluor(TM)
Synonym 1,3-Bis(2,6-diisopropylphenyl)-2-fluoroimidazolium Tetrafluoroborate

General Information

Product Number B5480

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Purity/Analysis Method >97.0%(N)
Storage Temperature
M.F. / M.W. C27H36BF5N2=494.40
CAS RN 2043361-32-4
Related CAS RN
MDL Number
Packaging and Container

Notes

Sold under PCT/US12/33125, licensed from President and Fellows of Harvard College.
  • Product Details
  • Safety & Regulations

Specification

Purity(with Total Nitrogen) min. 97.0 %

References

PubChem SID 354334448

GHS

Pictogram
Signal Word Danger
Hazard Statements
  • H314
  • :Causes severe skin burns and eye damage.
Precautionary Statements
  • P260
  • :Do not breathe dusts or mists.
  • P280
  • :Wear protective gloves, protective clothing, face protection.
  • P301+P330+P331+P310
  • :IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor.
  • P303+P361+P353+P310+P363
  • :IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse.
  • P304+P340+P310
  • :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor.
  • P305+P351+P338+P310
  • :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.

Transport Information

UN Number 1759
Class 8
Packing Group II
HS Number 2933299090

Application

AlkylFluorTM: Stable Reagent for Deoxyfluorination of Primary and Secondary Alcohols

Experimental procedure: An oven-dried vial is charged with potassium fluoride (58.1 mg, 1.00 mmol, 5.00 eq.) and AlkylFluor (118.7 mg, 0.240 mmol, 1.20 eq.), and heated at 100 °C for 1 h under vacuum (~0.1 mbar). The mixture is cooled to room temperature, then alcohol (0.200 mmol, 1.00 eq.) is added quickly. The vial is sealed, then evacuated and backfilled with nitrogen. Dioxane (3 mL) is added and the reaction mixture is heated at the appropriate temperature with vigorous stirring. Upon completion, the reaction mixture is cooled to room temperature and filtered through a pad of Celite, eluting with dichloromethane (3 × 1 mL). The filtrate is concentrated in vacuo and the residue is purified by flash column chromatography to afford the desired alkyl fluoride.

References

PubMed Literature

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