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N-Methyl-N-trimethylsilylacetamide [Trimethylsilylating Agent]
(CAS RN:7449-74-3 Product Number:M0536)

Structure

N-Methyl-N-trimethylsilylacetamide
Synonym N-Methyl-N-TMS-acetamide

General Information

Product Number M0536

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Purity/Analysis Method >90.0%(GC)
Storage Temperature 0-10°C
M.F. / M.W. C6H15NOSi=145.28
CAS RN 7449-74-3
Related CAS RN
MDL Number MFCD00040758
Packaging and Container 25g-Vial, (View image) 10g-Vial (View image)
  • Product Details
  • Safety & Regulations

Specification

Appearance Colorless to Light yellow clear liquid
Purity(GC) min. 90.0 %
Effect test of TMS derivatization Effective as derivatization agent Myristic Acid

Data of Reference

flp 48°C(lit.)
bp 154°C(lit.)

References

Beilstein 4(4)4011
Reaxys-RN 506975
PubChem SID 87572572
EC Number 231-217-0

GHS

Pictogram
Signal Word Danger
Hazard Statements
  • H226
  • :Flammable liquid and vapour.
  • H314
  • :Causes severe skin burns and eye damage.
Precautionary Statements
  • P260
  • :Do not breathe dusts or mists.
  • P301+P330+P331+P310
  • :IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor.
  • P303+P361+P353+P310+P363
  • :IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse.
  • P304+P340+P310
  • :IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor.
  • P305+P351+P338+P310
  • :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
  • P370+P378
  • :In case of fire: Use dry chemical or dry sand to extinguish.

Transport Information

UN Number 2924
Class 3/8
Packing Group III
HS Number 2931399090

Application

Reactivity of Trimethylsilylating Reagents : Trimethylsilylation of Alcohols

M0536

References

  • Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.

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