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Guanidine Nitrate
(CAS RN:506-93-4 Product Number:G0164)

Structure

Guanidine Nitrate

General Information

Product Number G0164

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Purity/Analysis Method >98.0%(W)
Storage Temperature
M.F. / M.W. CH5N3·HNO3=122.08
CAS RN 506-93-4
Related CAS RN
MDL Number MFCD00013028
Packaging and Container

Notes

Cannot be shipped to Israel, Turkey and Russia.
  • Product Details
  • Safety & Regulations

Specification

Appearance White to Almost white powder to crystal
Purity(Gravimetric Method) min. 98.0 %
Melting point 212.0 to 216.0 deg-C
Solubility in Water almost transparency

References

Beilstein 3,86
Reaxys-RN 3596600
PubChem SID 125309399
Merck Index(14) 4562
RTECS# MF4350000
EC Number 208-060-1

GHS

Pictogram
Signal Word Warning
Hazard Statements
  • H272
  • :May intensify fire; oxidizer.
  • H302
  • :Harmful if swallowed.
  • H315
  • :Causes skin irritation.
  • H319
  • :Causes serious eye irritation.
Precautionary Statements
  • P210
  • :Keep away from heat.
  • P220
  • :Keep/Store away from clothing/combustible materials.
  • P221
  • :Take any precaution to avoid mixing with combustibles.
  • P280
  • :Wear protective gloves, eye protection.
  • P302+P352+P332+P313+P362+P364
  • :IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. Take off contaminated clothing and wash it before reuse.
  • P305+P351+P338+P337+P313
  • :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

Transport Information

UN Number 1467
Class 5.1
Packing Group III
HS Number 2925290090

Application

Nitration of Aryl Compounds

Typical Procedure:
To a well-stirred mixture of aromatic compound (0.01 mol) and 85% sulfuric acid (15 mL) is slowly added guanidine nitrate (1.22 g, 0.01 mol) while maintaining the temperature at 0-5 ℃. After the addition of guanidine nitrate is complete, the mixture is stirred for an additional 0.5-3 h at the same temperature or at rt (for Entry 4). The reaction mixture is poured onto ice water (100 mL) and in the case of Entry 3, it is poured onto ice cold 20% NaOH solution (100 mL). The solid obtained is filtered, washed thoroughly with water and dried. Where solid is not obtained, the aqueous layer is extracted with CHCl3 (4 x 50 mL). The combined CHCl3 layer is washed with 10% Na2CO3 (2 x 25 mL), water (2 x 25 mL) and then dried (anhyd. Na2SO4). After evaporation of the solvent, a brown residue is obtained, which is purified by column chromatography to afford the corresponding nitro compound.

References

PubMed Literature

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