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1,1'-Bis(diphenylphosphino)ferrocene
(CAS RN:12150-46-8 Product Number:B2027)

Structure

1,1'-Bis(diphenylphosphino)ferrocene
Synonym 1,1'-Ferrocenebis(diphenylphosphine)

General Information

Product Number B2027

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Purity/Analysis Method >96.0%(T)
Storage Temperature
M.F. / M.W. C34H28FeP2=554.39
CAS RN 12150-46-8
Related CAS RN
MDL Number MFCD00001422
  • Product Details
  • Safety & Regulations
  • Reference & Application

Specification

Appearance Light yellow to Brown powder to crystaline
Purity(Chelometric Titration) min. 96.0 %

References

PubChem SID 87564906

GHS

Pictogram
Signal Word Warning
Hazard Statements
  • H302+H312+H332
  • :Harmful by inhalation, in contact with skin and if swallowed.
Precautionary Statements
  • P261
  • :Avoid breathing dust, fume, mist, vapors or spray.
  • P264
  • :Wash hands and face thoroughly after handling.
  • P270
  • :Do not eat, drink or smoke when using this product.
  • P271
  • :Use only outdoors or in a well-ventilated area.
  • P280
  • :Wear protective gloves, protective clothing.
  • P301+P312+P330
  • :If swallowed: Call a poison center or doctor if you feel unwell. Rinse mouth.
  • P302+P352+P312+P362+P364
  • :If on skin: Wash with plenty of soap and water. Call a poison center or doctor if you feel unwell. Take off contaminated clothing and wash it before reuse.
  • P304+P340+P312
  • :If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell.
  • P501
  • :Dispose of contents and container in accordance with local, regional, national regulations (e.g. US: 40 CFR Part 261, EU:91/156/EEC, JP: Waste Disposal and Cleaning Act, etc.).

Transport Information

HS Number 2931.90.6000

Application

Synthesis of Carbinols

Typical procedure: Under an air atmosphere, a Schlenk tube is charged with Cu(OAc)2•H2O (4.0 mg, 0.02 mmol), dppf (16.6 mg, 0.03 mmol), arylboronic acid (0.4 mmol), aldehyde (0.2 mmol), NaOAc (49.2 mg, 0.6 mmol), and toluene (3 mL) under ice-salt (-20 ºC). The mixture is stirred for 0.5 h at room temperature, refluxed for 24 h, and then cooled in a Schlenk tube to room temperature. The mixture is extracted with ethyl acetate (4×5 mL), and the organic layers are washed with water. The organic layers are dried over MgSO4, concentrated, and purified by flash column chromatography on silica gel to give the desired product.

References

PubMed Literature

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