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[1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride
(CAS RN:19978-61-1 제품번호:B2016)

구조식

[1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride
동의어의 [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
동의어의 Dichloro[1,2-bis(diphenylphosphino)ethane]palladium(II)

일반 정보

제품번호 B2016

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순도/분석 방법 >98.0%(T)
보관 온도
M.F. / M.W. C26H24Cl2P2Pd=575.75
CAS RN 19978-61-1
관련 CAS RN
MDL 번호 MFCD00015702
용기
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  • 안전 및 규정
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규격

Appearance White to Yellow to Green powder to crystal
Purity(Chelometric Titration) min. 98.0 %
Purity(Argentmetric Titration) min. 98.0 %

참조

Reaxys-RN 14861078
PubChem SID 87564896

GHS

픽토그램
신호 워드 Warning
위험물 및 유해 등록
  • H302+H312+H332
  • :Harmful by inhalation, in contact with skin and if swallowed.
  • H315
  • :Causes skin irritation.
  • H319
  • :Causes serious eye irritation.
주의 사항
  • P261
  • :Avoid breathing dust, fume, mist, vapors or spray.
  • P264
  • :Wash hands and face thoroughly after handling.
  • P270
  • :Do not eat, drink or smoke when using this product.
  • P271
  • :Use only outdoors or in a well-ventilated area.
  • P280
  • :Wear protective gloves, protective clothing, eye protection.
  • P301+P312+P330
  • :If swallowed: Call a poison center or doctor if you feel unwell. Rinse mouth.
  • P302+P352+P312+P362+P364
  • :If on skin: Wash with plenty of soap and water. Call a poison center or doctor if you feel unwell. Take off contaminated clothing and wash it before reuse.
  • P304+P340+P312
  • :If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell.
  • P305+P351+P338+P337+P313
  • :If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.
  • P501
  • :Dispose of contents and container in accordance with local, regional, national regulations (e.g. US: 40 CFR Part 261, EU:91/156/EEC, JP: Waste Disposal and Cleaning Act, etc.).

이용 예

Palladium-catalyzed Cyanation of Aryl Halides

B2016

Typical Procedure:
Under air, a Schlenk tube is charged with CuSCN (60.8 mg, 0.5 mmol), aryl iodides (0.7 mmol, 1.25 eq.), PdCl2(dppe) (2.9 mg, 1 mol%), HCOONa (102.0 mg, 3.0 eq.), HCOOH (2.0 μL, 10 mol%), and DMSO/H2O = 8 : 1 (3.0 mL). The mixture is stirred at 100 °C (oil bath temperature) for 36 h, or until complete consumption of starting material as monitored by TLC or GC-MS analysis. The reaction mixture is allowed to cool to room temperature, poured into brine (20 mL), and extracted with EtOAc (4 × 5 mL). The combined organic layers are washed with water and dried over MgSO4, and the solvents are removed under vacuum. The residue is purified by flash column chromatography (petroleum ether―ethyl acetate) to afford the desired product.

References

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