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Chloromethyl Methyl Ether
(CAS RN:107-30-2 產品號碼:C0202)

結構式

Chloromethyl Methyl Ether
別名 (英文) Chlorodimethyl Ether
別名 (英文) Methoxymethyl Chloride

基本信息

產品號碼 C0202

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純度/分析方法 >95.0%(GC)
儲藏溫度 0-10 °C
分子式 / 分子量 C2H5ClO=80.51
CAS RN 107-30-2
相關CAS RN
MDL號碼 MFCD00000885
包裝
  • 產品詳細信息
  • 安全&法規
  • 文獻&應用

規格

Purity(GC) min. 95.0 %
Specific gravity (20/20) 1.0680 to 1.0790
Refractive index n20/D 1.3920 to 1.4010
Bis chloromethyl ether(GC) max. 1.0 %

參考值

flp -6°C
mp -104°C(lit.)
bp 59°C(lit.)

文獻

Beilstein 1,580
Reaxys-RN 505943
PubChem SID 125308726
Merck Index(14) 2146
F&F 9,107
RTECS# KN6650000

GHS

圖形表示
提示語 Danger
危險有害信息
  • H225
  • :Highly flammable liquid and vapor.
  • H301
  • :Toxic if swallowed.
  • H314
  • :Causes severe skin burns and eye damage.
  • H330
  • :Fatal if inhaled.
  • H350
  • :May cause cancer.
  • H370
  • :Causes damage to Respiratory System.
  • H373
  • :May cause damage to Respiratory System through prolonged or repeated exposure.
注意
  • P201
  • :Obtain special instructions before use.
  • P202
  • :Do not handle until all safety precautions have been read and understood.
  • P210
  • :Keep away from heat, sparks, open flames and hot surfaces. – No smoking.
  • P233
  • :Keep container tightly closed.
  • P240
  • :Ground and bond container and receiving equipment.
  • P241+P242+P243
  • :Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge.
  • P260
  • :Do not breathe mist, vapors or spray.
  • P264
  • :Wash hands and face thoroughly after handling.
  • P270
  • :Do not eat, drink or smoke when using this product.
  • P271
  • :Use only outdoors or in a well-ventilated area.
  • P280
  • :Wear protective gloves, protective clothing, face protection.
  • P284
  • :Wear respiratory protection.
  • P301+P330+P331+P310
  • :If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor.
  • P303+P361+P353+P310+P363
  • :If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a poison center or doctor. Wash contaminated clothing before reuse.
  • P304+P340+P310
  • :If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a poison center or doctor.
  • P305+P351+P338+P310
  • :If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor.
  • P308+P311
  • :If exposed or concerned: Call a poison center or doctor.
  • P370+P378
  • :In case of fire: Use dry chemical, dry sand or foam to extinguish.
  • P403+P233
  • :Store in a well-ventilated place. Keep container tightly closed.
  • P405
  • :Store locked up.
  • P501
  • :Dispose of contents and container in accordance with local, regional, national regulations (e.g. US: 40 CFR Part 261, EU:91/156/EEC, JP: Waste Disposal and Cleaning Act, etc.).

交通信息

 UN 號碼 1239
類別 6.1/3
航空運輸 空運禁止

應用

MOM protection of Alcohols using Methoxymethyl Chloride and Sodium Iodide

References

  • Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.

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