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C-H键活化反应 [合成试剂] / C-H Bond Activation Reaction [Synthetic Reagents]

 Recently, there have been a large number of reports on "C-H bond activation reaction". C-H bond activation is a methodology for directly forming carbon-carbon bonds by activating a carbon-hydrogen bond, which is the most fundamental linkage in organic chemistry. Traditional cross coupling reactions have been one of the most useful synthetic methods for the formation of carbon-carbon bonds. However, the cross coupling reaction requires extra procedures for preparing organic halides (or triflates) compounds, and organic boron or metal compounds. On the other hand, the C-H bond activation can reduce these procedures, thus making this reaction a cost-effective and eco-friendly system.
 C-H bonds generally have relatively high energy, therefore, the formation of a carbon-carbon or carbon-heteroatom bond by dissecting C-H bonds has been believed to be difficult. In 1993, Murai et al. reported the direct addition of C-H bonds of aromatic ketones to olefins in the presence of a catalytic amount of carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II) [C2251].1) Since then, numerous examples of C-H bond activation have been reported.
 The reaction above proceeds without using halogenated compounds and organic boron or organic metal compounds. Thus, this system is cost-effective and eco-friendly.

The brochure is in the link below.
A0419
8-Aminoquinoline
A1479
Allylpalladium(II) Chloride Dimer
A2761
(Acetylacetonato)(norbornadiene)rhodium(I)
B0034
Nickel(II) Benzenesulfonate Hexahydrate
B0089
1,4-Benzoquinone
B0468
2,2'-Bipyridyl
B1174
1,2-Bis(dimethylphosphino)ethane
B1313
[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride
B1571
Bis(triphenylphosphine)nickel(II) Dichloride
B1667
Bis(triphenylphosphine)palladium(II) Dichloride
B1668
Bis(benzonitrile)palladium(II) Dichloride
B2026
Bis(tri-o-tolylphosphine)palladium(II) Dichloride
B2042
Bis(triphenylphosphine)palladium(II) Diacetate
B2064
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct
B2225
[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride
B2226
[1,1'-Bis(diphenylphosphino)ferrocene]nickel(II) Dichloride
B2709
4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene
B2710
1,1'-Bis(diisopropylphosphino)ferrocene
B3235
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride
B3351
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene](1,3-diphenyl-1,3-propanedionato)copper(I)
B3354
Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide
B3534
Bis(tricyclohexylphosphine)nickel(II) Dichloride
B4467
trans,trans-1,5-Bis(4-methoxyphenyl)-1,4-pentadien-3-one
B4468
trans,trans-1,5-Bis[4-(trifluoromethyl)phenyl]-1,4-pentadien-3-one
C0384
Bis(2,4-pentanedionato)copper(II)
C2160
Cesium Carbonate
C2304
Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)
C2346
Copper(II) Acetate Monohydrate
C2405
Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I)
C2662
(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
C3041
Chlorobis(ethylene)iridium(I) Dimer
D0686
p-Xyloquinone
D0720
N,N'-Dimethylethylenediamine
D0798
Dimethyl Sulfoxide
D0905
Bathophenanthroline
D2234
2,6-Dimethyl-1,4-benzoquinone
D2411
Dicyclohexylphenylphosphine
D2604
Dichloro(1,5-cyclooctadiene)palladium(II)
D3134
4,4'-Di-tert-butyl-2,2'-bipyridyl
D3389
2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl
D3411
Di-tert-butyl Peroxide
D3891
Dichloro(1,10-phenanthroline)copper(II)
D4264
2-(Diisopropylsilyl)pyridine
D4652
trans-2,6-Diisopropyl-N-(2-pyridylmethylene)aniline
D4731
Di-tert-butyl(methyl)phosphonium Tetrafluoroborate
I0079
Tris(2,4-pentanedionato)iron(III)
L0224
Lithium Carbonate
N0096
Bis(2,4-pentanedionato)nickel(II) Hydrate
N0166
2-Norbornene
N0842
2,5-Norbornadiene Palladium(II) Dichloride
N0850
Nickel(II) Chloride Anhydrous
P1489
Palladium(II) Chloride
P1748
Potassium Carbonate
P1763
(Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer
P1902
2-(1H-Pyrazol-5-yl)aniline
S0463
Silver Hexafluoroantimonate(V)
S0898
Silver Bis(trifluoromethanesulfonyl)imide
S0978
Sodium Pivalate Hydrate
T0276
Nickel(II) p-Toluenesulfonate Hexahydrate
T0361
Tributylphosphine
T0431
Trifluoroacetic Acid
T1024
Tri(o-tolyl)phosphine
T1244
p-Toluquinone
T1292
Copper(II) Trifluoromethanesulfonate
T1442
Copper(I) Trifluoromethanesulfonate Benzene Complex
T1560
2,2,6,6-Tetramethylpiperidine 1-Oxyl Free Radical
T1614
Tris(2,6-dimethoxyphenyl)phosphine
T1643
Tri(2-furyl)phosphine
T2557
Tris(2,4-pentanedionato)iridium(III)
T2584
Tri-tert-butylphosphonium Tetrafluoroborate

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