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CAS RN: 32248-43-4 | 產品號碼: S0494
Samarium(II) Iodide (ca. 0.1mol/L in Tetrahydrofuran)
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* TCI會時常優化儲存條件,儲存溫度請以在線目錄為準，敬請留意。
補充產品訊息:
Both 100mL bottles of this product is attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".
| 產品號碼 | S0494 |
| 分子式 / 分子量 | SmI__2 = 404.17 |
| 外觀與形狀（20°C） | Liquid |
| 儲存條件 | Room Temperature (Recommended in a cool and dark place, <15°C) |
| 儲存在惰性氣體下 | Store under inert gas |
| 應避免的情況 | Air Sensitive,Moisture Sensitive |
| 包裝和容器 | 25ML-DualSeal Bottle （閲覽圖片） |
| CAS RN | 32248-43-4 |
| PubChem Substance ID | 87558542 |
| Merck Index(14) | 8349 |
產品規格
| Appearance | Blue to Dark blue clear liquid to cloudy liquid |
| Concentration(Titration) | 0.075 to 0.110 mol/L |
性質
| 比重 | 0.92 |
GHS
| 圖形表示 |
|
| 信號詞 | Danger |
| 危險性說明 | H302 : Harmful if swallowed. H315 : Causes skin irritation. H319 : Causes serious eye irritation. H371 : May cause damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H351 : Suspected of causing cancer. H335 : May cause respiratory irritation. H225 : Highly flammable liquid and vapor. |
| 防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P201 : Obtain special instructions before use. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
相關法規
運輸資料
| UN編號 | UN2056 |
| 類別 | 3 |
| 包裝類別 | II |
| HS編碼* | 3822.19-000 |
Application
Tandem SmI2-induced beta-elimination / aldol-type reaction
Typical procedure: Nitrone 1 (50 mg) is co-evaporated with toluene (1 mL x 3) at 35 °C then is deoxygenated. To the solution of 1 in dry THF (0.5 mL), a 0.1 mol/L THF solution of SmI2 (2.0 mL) is added at -60 °C under argon. After disappearance of the typical blue color, cyclohexanecarboxaldehyde (25 micro L) is added and the temperature is raised to room temperature over 5 h. A saturated aqueous solution of Na2S2O3 (2 mL), a saturated aqueous solution of NaHCO3 (2 mL) and EtOAc (2 mL) are added. The aqueous phase is extracted with EtOAc (20 mL x 2), and the combined extracts are dried over MgSO4. Concentration gives a crude oil. Purification by silica gel chromatography (eluent: pentane/EtOAc=6/1 to 0/1 then EtOAc/MeOH=8/1) gives 3 (39 mg, 77%) as a pale yellow oil.
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