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Products > Featured Products >

Tridentate Phosphine Ligand for Catalytic C-H Methylation

Bis[2-(diphenylphosphino)phenyl]phenylphosphine

Product

B6436: Bis[2-(diphenylphosphino)phenyl]phenylphosphine

Advantages

High-purity tridentate ligand manufactured with introducing technology of ENEOS Corporation
Stable against heat and moisture
Forms iron complex to catalyze C-H methylation at ortho-position of arenes with a carbonyl group

Application

Iron Catalytic C-H Methylation using B6436 as a ligand

Reference

Iron-Catalyzed Ortho C–H Methylation of Aromatics Bearing a Simple Carbonyl Group with Methylaluminum and Tridentate Phosphine Ligand
- R. Shang, L. Ilies, E. Nakamura, J. Am. Chem. Soc. 2016, 138, 10132.

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I0079: Tris(2,4-pentanedionato)iron(III) (= Fe(acac)₃)

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Tridentate Phosphine Ligand for Catalytic C-H Methylation (PDF file)