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CAS RN: 130004-33-0 | Product Number: R0147
[RuCl(p-cymene)((S)-binap)]Cl
![Thumbnail of [RuCl(p-cymene)((S)-binap)]Cl](/medias/R0147.jpg?context=bWFzdGVyfHJvb3R8MTM0NzN8aW1hZ2UvanBlZ3xhRGs0TDJnM1pTODRPVE0yTlRrMU9URTBOemd5TDFJd01UUTNMbXB3Wnd8NmFmOGFjNzlkNDU1MjA0YjRkMDVjMzI2Y2I5NTU1OWI1YzQxMjIxOGM2ZGM5ZDc2MWFkM2JjNzhjZWQwZGZhMQ "[RuCl(p-cymene)((S)-binap)]Cl")
![Chemical Structure of [RuCl(p-cymene)((S)-binap)]Cl](/medias/R0147.jpg?context=bWFzdGVyfHJvb3R8NDU3NDN8aW1hZ2UvanBlZ3xhREV5TDJnNE1pODRPVEl6TVRJNE56a3hNRGN3TDFJd01UUTNMbXB3Wnd8NmFkMzc4NmMwOTU3NjY3MDk3NTE2MTkwMmUzZjZmMWU3ZGFhNWZjZGFkNDhkMWMwOTVjN2ExMjQyOWY2NDQ3Yw "[RuCl(p-cymene)((S)-binap)]Cl")
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![[RuCl(p-cymene)((S)-binap)]Cl](/_ui/responsive/theme-tci/images/missing_product_zoom.webp "[RuCl(p-cymene)((S)-binap)]Cl")
Purity: >90.0%(HPLC)
Synonyms:
- Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 200MG |
€32.00
|
1 | 8 |
|
|
| 1G |
€110.00
|
Contact Us | 7 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
Supplemental Product Information:
This product was merchandised under the technical tie-up with TAKASAGO INTERNATIONAL CORPORATION.
We offer this product only in quantities for laboratory use.
| Product Number | R0147 |
Purity / Analysis Method 
|
>90.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__5__4H__4__6Cl__2P__2Ru = 928.88 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 130004-33-0 |
| Reaxys Registry Number | 16702130 |
| PubChem Substance ID | 253662112 |
| MDL Number | MFCD00134456 |
Specifications
| Appearance | White to Brown to Dark purple powder to crystal |
| Purity(HPLC) | min. 90 area% |
Properties (reference)
| Solubility in water | Insoluble |
GHS
Related Laws:
Transport Information:
| HS Number | 2843909000 |
Application
An efficient ruthenium catalyst usable for high enatioselective hydrogenation of ketones
References
- Homogeneous asymmetric hydrogenation of o-chloroacetophenone to enantiomerically pure o -chloro-(1-phenyl)ethanol catalyzed by BINAP-Ru(II) complex
- Cationic BINAP-Ru(II) Halide Complexes: Highly Efficient Catalysts for Stereoselective Asymmetric Hydrogenation of .alpha.- and .beta.-Functionalized Ketones
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