TCIMAIL Back Numbers 2012

Syntheses of Catechol Diterpenes and Their Biological Activities[PDF : 802KB]
Masahiro Tada,
Professor Emeritus, Tokyo University of Agriculture and Technology

Useful Organocatalyst for Acid-free Acetalization

1,8-Diaminonaphthalene-masked Boronic Acids

Stable Fluorinating Reagent with Ease of Handling “FLUOLEAD™"

Useful N-Heterocyclic Carbene Precatalysts “Bode Catalysts”

Reduction of Alcohols

Strong Organic Bases

A Useful Brominating Reagent

A Useful Condensation Activator Bearing Less Nucleophilicity and No Deliquescence

Selective Fluorination of Hydroxy Group using DFMBA

Electrophilic Iodinating Reagent

Air-Stable Tri-tert-butylphosphine Equivalent

Reagent of the Preparation for Water-Soluble Labels

N-Mesityl Substituted Chiral Triazolium Salts: Opening a New World of N-Heterocyclic Carbene Catalysis[PDF : 998KB]
Pei-Chen Chiang, Graduate student, Department of Chemistry, University of Pennsylvania
Jeffrey W. Bode, Professor, Laboratorium für Organische Chemie, ETH-Zürich

New Organic Functional Material "Picene"

Building Block for Organic Photovoltaic Cell Polymers

Ion-supported Triphenylphosphine

Useful Chiral Auxiliaries for the Synthesis of Chiral Oxiranes

Glycosyl Donor

(IMes)-Copper Complex for Methylenation and Grignard Reactions

Short Topic: More ways to use reagents | Ring-Closing Metathesis Using Tebbe or Petasis Reagent

Dehydrative Intramolecular Condensation Catalyst for the Synthesis of Carboxylic Anhydrides

Precursor of the Chiral Hypervalent Iodine Catalyst

Application to the Synthesis of [5,5] Carbon Nanotube

A Valuable Synthetic Intermediate of 5-Substituted Resorcinols

Fluorescent Label

Chemiluminescence Enhancer

A Synthetic Biology Approach to the Expansion of the Genetic Alphabet: Molecular Design of Unnatural Base Pairs of DNA[PDF : 1.3MB]
Ichiro Hirao, Team Leader,
Michiko Kimoto, Researcher,
Nucleic Acid Synthetic Biology Research Team, RIKEN SSBC

A Valuable Synthetic Intermediate for 2-Substituted Adenosine

Indicator Nucleoside of DNA Methylation

A Unique and Efficient Ni Catalyst for Cross-Coupling Reactions

Useful DMAP Analogs

Reagent for Introduction of the TTMSS Group

Bifunctional Molecular Catalysts with Cooperating Amine/Amido Ligands[PDF : 571KB]
Yoshihito Kayaki, Assistant Professor,
Takao Ikariya, Professor,
Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology

Air-Stable Phophine Oxide Ligand

Allylic C–H Oxidation•Amination Catalyst “White Catalyst”

Powerful and Easy Peptide Coupling Reagent

Synthesis of Diazo Compounds

Chemoselective Reduction of Aldehydes

Recent Researches on Construction of Artificial Helical Polymers Practical Molecular Design Methodology by the Factors for Inducing and Maintaining Helical Structures on the Basis of Classification of Main Chain Skeleton[PDF : 2.5MB]
Akiko Okamoto, Assistant Professor,
Hideaki Oike, Assistant Professor,
Noriyuki Yonezawa, Professor,
Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology

Direct Aldol Reactions by Asymmetric Organocatalyst in Water

Air Stable Diaminophosphine Oxide Ligands for Transition Metal Catalyzed Cross-Coupling Reactions

A New Electrophilic Trifluoromethylating Reagent

Reagents for Introduction of the Teoc-Protecting Group

Easy-to-Handle and Safe Phosphitylation Reagent for Syntheses of DNA and RNA Fragments

Metal-Free Reduction of Tertiary Amides