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Pyridinesulfinates, Pyrimidinesulfinates [Cross-coupling Reaction using Transition Metal Catalysts]

Pyridinesulfinates ― Surrogates of Pyridineboronates
 Pyridine-2-sulfinates and pyrimidine-2-sulfinates can be utilized in Suzuki-Miyaura cross coupling reagents as replacements for pyridine-2-boronic acids and pyrimidine-2-boronic acids, which are difficult to prepare. These reagents are tolerated by ketone, ester, trifluoromethyl, and other functional groups.1,2) Also the cross-coupling reaction with Grignard reagents proceeds without transition metals.3) It has been reported that these reagents are applied to late-stage modifications in drug discovery, and ligand syntheses for catalytic reactions.
Cross-coupling using Pyridine-2-sulfinates, Pyrimidine-2-sulfinates


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Artikel # O0541
CAS RN 2188151-68-8
Reinheit >97.0%(T)(HPLC)

Artikel # A3344
CAS RN 2249891-90-3
Reinheit >98.0%(GC)(N)

Artikel # O0533
CAS RN 24367-66-6
Reinheit >95.0%(T)

Artikel # O0539
CAS RN 116008-37-8
Reinheit >95.0%(T)(HPLC)

Artikel # A3349
CAS RN 2249891-88-9
Reinheit >95.0%(GC)

Artikel # A3343
CAS RN 2249891-89-0
Reinheit >98.0%(GC)(T)

Artikel # A3350
CAS RN 2249891-86-7
Reinheit >98.0%(GC)