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CAS RN: 127783-36-2 | Product Number: P1239
Trimethylsilylethynyl(phenyl)iodonium Tetrafluoroborate
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Purity: >98.0%(T)
Synonyms:
- Phenyl(trimethylsilylethynyl)iodonium Tetrafluoroborate
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 1G |
69,00 €
|
Contact Us | ≥40 |
|
|
| 5G |
242,00 €
|
1 | 23 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
| Product Number | P1239 |
Purity / Analysis Method 
|
>98.0%(T) |
| Molecular Formula / Molecular Weight | C__1__1H__1__4BF__4ISi = 388.03 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Frozen (<0°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Moisture Sensitive,Heat Sensitive |
| CAS RN | 127783-36-2 |
| Reaxys Registry Number | 3580345 |
| PubChem Substance ID | 87575335 |
| MDL Number | MFCD00191578 |
Specifications
| Appearance | White to Light yellow to Light orange powder to crystal |
| Purity(Argentometric Titration) | min. 98.0 % |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H314 : Causes severe skin burns and eye damage. |
| Precautionary Statements | P260 : Do not breathe dust. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
Transport Information:
| UN Number | UN1759 |
| Class | 8 |
| Packing Group | II |
| HS Number | 2931900090 |
Application
Hypervalent Iodine Reagent Useful for the Chemical Synthesis of Diatomic Carbon
References
- 1) Synthesis of ethynyl(phenyl)iodonium tetrafluoroborate. A new reagent for ethynylation of 1,3-dicarbonyl compounds
- 2) Room-temperature chemical synthesis of C2
- 3) Synthesis of N-(acyloxy)-N-alkynylamides via generation of “C2” from hypervalent alkynyliodane and a weak base
- 4) Routes involving no free C2 in a DFT-computed mechanistic model for the reported room-temperature chemical synthesis of C2
- 5) A combined DFT-predictive and experimental exploration of the sensitivity towards nucleofuge variation in zwitterionic intermediates relating to mechanistic models for unimolecular chemical generation and trapping of free C2 and alternative bimolecular pathways involving no free C2
PubMed Literature
Product Articles
[Product Highlights] Hypervalent Iodine Reagent Useful for the Chemical Synthesis of Diatomic Carbon
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