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Published TCIMAIL newest issue No.201
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CAS RN: 492-08-0 | Product Number: S0884
(+)-Sparteine
×
Purity: >98.0%(GC)
Synonyms:
- Pachycarpine
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 1G |
€88.00
|
6 | 8 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
| Product Number | S0884 |
Purity / Analysis Method 
|
>98.0%(GC) |
| Molecular Formula / Molecular Weight | C__1__5H__2__6N__2 = 234.39 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Heat Sensitive |
| CAS RN | 492-08-0 |
| Reaxys Registry Number | 82448 |
| PubChem Substance ID | 160871001 |
| MDL Number | MFCD00869353 |
Specifications
| Appearance | Colorless to Light orange to Yellow clear liquid |
| Purity(GC) | min. 98.0 % |
| Optical purity(GC) | min. 99.0 ee% |
| NMR | confirm to structure |
Properties (reference)
| Boiling Point | 174 °C/8 mmHg |
| Flash point | 148 °C |
| Specific Rotation | 18° (C=1,EtOH) |
| Refractive Index | 1.53 |
| Maximum Absorption Wavelength | 202 nm (CH__3CN) |
| Solubility (slightly sol. in) | Ethanol |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H302 : Harmful if swallowed. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P270 : Do not eat, drink or smoke when using this product. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. |
Related Laws:
| RTECS# | RT0620000 |
Transport Information:
| HS Number | 2939799090 |
Application
Sparteines as Chiral Ligands for Asymmetric Synthesis
References
- 1)Review of (?)-sparteine as a chiral ligand for metal catalysts
- 2)Review of enantioselective synthesis with Li/(?)-sparteine carbanion pairs
- 3)Asymmetric lithiation of (?)-sparteine and (+)-sparteine
- 4)Asymmetric aldol additions using (?)-sparteine and TiCl4
- 5)Palladium-catalyzed oxidative kinetic resolutions of secondary alcohols with (?)-sparteine
- 6)Enantiomer-selective polymerizations using (?)-sparteine
Application
Total Synthesis of (+)-Sparteine
References
- First Asymmetric Total Synthesis of (+)-Sparteine
- Asymmetric total synthesis of (+)-sparteine and the synthesis of a readily accessible (+)-sparteine surrogate
- R. Iyengar, V. Gracias, Chemtracts 2004, 17, 92.
PubMed Literature
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