Published TCIMAIL newest issue No.199
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CAS RN: 2010983-27-2 | Product Number: D3475
6,10-Dibenzyl-N,N'-dimethyl-N,N,N',N'-tetrakis(4-methylbenzyl)-1,4-dioxaspiro[4.5]decane-(2R,3R)-diylbis(methylammonium) Bis(tetrafluoroborate) [=(R,R)-TaDiAS-2nd]
Purity: >97.0%(N)
Synonyms:
- (R,R)-TaDiAS-2nd
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 200MG |
€148.00
|
1 | 3 |
|
| 1G |
€738.00
|
1 | 7 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | D3475 |
Purity / Analysis Method
|
>97.0%(N) |
| Molecular Formula / Molecular Weight | C__5__8H__7__0B__2F__8N__2O__2 = 1,000.82 |
| Physical State (20 deg.C) | Solid |
Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Hygroscopic |
Packaging and Container
|
200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 2010983-27-2 |
| PubChem Substance ID | 87559773 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(with Total Nitrogen) | min. 97.0 % |
| NMR | confirm to structure |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H314 : Causes severe skin burns and eye damage. |
| Precautionary Statements | P260 : Do not breathe dust. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
Transport Information:
| UN Number | UN1759 |
| Class | 8 |
| Packing Group | III |
| HS Number | 2932990090 |
Application
Asymmetric Two-center Phase-transfer Catalyst

References
- T. Shibuguchi, H. Mihara, A. Kuramochi, S. Sakuraba, T. Ohshima, M. Shibasaki, Angew. Chem. Int. Ed. 2006, 45, 4635.

- H. Mihara, T. Shibuguchi, A. Kuramochi, T. Ohshima, M. Shibasaki, Heterocycles 2007, 72, 421.

PubMed Literature
Product Articles
[TCIMAIL No.135] Asymmetric Two-center Phase-transfer Catalyst[TCIMAIL No.135] Benzyne Precursors
Product Documents (Note: Some products will not have analytical charts available.)
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![Thumbnail of 6,10-Dibenzyl-N,N'-dimethyl-N,N,N',N'-tetrakis(4-methylbenzyl)-1,4-dioxaspiro[4.5]decane-(2R,3R)-diylbis(methylammonium) Bis(tetrafluoroborate) [=(R,R)-TaDiAS-2nd]](/medias/D3475.jpg?context=bWFzdGVyfHJvb3R8MTYwNjV8aW1hZ2UvanBlZ3xhRGt4TDJoak1DODRPVE0wTnpRd01EWTJNek0wTDBRek5EYzFMbXB3Wnd8MDI4NjE3ZDkwNzNjMzlmMDU4ODk1YTVlYjU1MDUwYWEwYTQyZDlmOTIwNzc4ZjA3ZjEyMjY5NzlmNTdlYmRlZA)