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CAS RN: 527-21-9 | Product Number: T0790

Tetrafluoro-1,4-benzoquinone


Purity: >98.0%(T)(HPLC)
Synonyms:
  • Fluoranil
Documents:
1G
€39.00
4   14  
5G
€132.00
5   16  

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Product Number T0790
Purity / Analysis Method >98.0%(T)(HPLC)
Molecular Formula / Molecular Weight C__6F__4O__2 = 180.06  
Physical State (20 deg.C) Solid
CAS RN 527-21-9
Reaxys Registry Number 1875039
PubChem Substance ID 87576632
SDBS (AIST Spectral DB) 5440
MDL Number

MFCD00001592

Specifications
Appearance Light yellow to Brown powder to crystal
Purity(HPLC) min. 98.0 area%
Purity(Iodometric Titration) min. 98.0 %
Solubility in Toluene almost transparency
Properties (reference)
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws: / Compliance with laws, Regulations
Enzyme Commission 208-411-9
Transport Information:
HS Number 2914790090
Application
Mukaiyama Oxidation-Reduction Condensation

T0790

[Experimental procedure]
to a mixture of alkoxydiphenylphosphine (2, 0.60 mmol), prepared from the alcohol (1), n-BuLi and chlorodiphenylphosphine, and tetrafluoro-1,4-benzoquinone (0.72 mmol) under argon atmosphere is added a dichloromethane (0.50 mL) solution of alcohol (3, 0.72 mmol) at room temperature. After the reaction that is monitored by TLC was completed, the reaction mixture is quenched by adding water and the aqueous layer is extracted with dichloromethane. The organic layers are dried over anhydrous sodium sulfate. After filtration and evaporation, the resulted residue is purified by preparative TLC to afford the corresponding ether (4).

References


PubMed Literature


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