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CAS RN: 4648-54-8 | Product Number: T0801

Trimethylsilyl Azide


Purity: >95.0%(GC)
Synonyms:
  • Azidotrimethylsilane
Documents:
5G
€20.00
5   ≥20 
25G
€59.00
13   ≥20 
100G
€178.00
1   ≥20 

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Product Number T0801
Purity / Analysis Method >95.0%(GC)
Molecular Formula / Molecular Weight C__3H__9N__3Si = 115.21  
Physical State (20 deg.C) Liquid
Storage Temperature 0-10°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive,Heat Sensitive
CAS RN 4648-54-8
Reaxys Registry Number 1903730
PubChem Substance ID 87576642
SDBS (AIST Spectral DB) 5295
MDL Number

MFCD00001986

Specifications
Appearance Colorless to Light yellow clear liquid
Purity(GC) min. 95.0 %
Properties (reference)
Boiling Point 97 °C
Flash point 6 °C
Specific Gravity (20/20) 0.88
Refractive Index 1.42
GHS
Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H301 + H311 + H331 : Toxic if swallowed, in contact with skin or if inhaled.
H341 : Suspected of causing genetic defects.
H225 : Highly flammable liquid and vapour.
Precautionary Statements P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P201 : Obtain special instructions before use.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
Related Laws:
EC Number 225-078-5
Transport Information:
UN Number UN1992
Class 3 / 6.1
Packing Group II
HS Number 2931399090
Application
Trimethylsilylation of Alcohols using TMS Reagents

T0801

References

  • Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


Application
TMS Protection of Alcohols using Azidotrimethylsilane

T0801

References

  • Efficient O-Trimethylsilylation of Alcohols and Phenols with Trimethylsilyl Azide Catalyzed by Tetrabutylammonium Bromide under Neat Conditions
  • Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


Application
Trimethylsilyl Azide for Azidation/curtius Rearrangement

References


Application
Trimethylsilyl Azide for Azidations

References


PubMed Literature


TCIMAIL
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