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CAS RN: 14024-18-1 | Product Number: I0079

Tris(2,4-pentanedionato)iron(III)


Purity: >98.0%(T)
Synonyms:
  • Acetylacetone Iron(III) Salt
  • Ferric(III) Acetylacetonate
  • Iron(III) Acetylacetonate
Documents:
25G
$28.00
38   ≥80 
100G
$75.00
3   31  
500G
$225.00
11   3  

* Please contact our distributors or TCI to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.


Product Number I0079
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__1__5H__2__1FeO__6 = 353.17 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
CAS RN 14024-18-1
PubChem Substance ID 87571482
SDBS (AIST Spectral DB) 4155
MDL Number

MFCD00000020

Specifications
Appearance Red to Dark red to Brown powder to crystal
Purity(Chelometric Titration) min. 98.0 %
Properties (reference)
Melting Point 185 °C(dec.)
Solubility in water Slightly soluble
Solubility (soluble in) Ethanol, Acetone, Benzene, dichloromethane, Toluene, Chloroform
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H302 : Harmful if swallowed.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P270 : Do not eat, drink or smoke when using this product.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
Related Laws:
RTECS# NO8960000
Transport Information:
H.S.code* 2914.19-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
2-PySO2CF2H : Bench-stable Difluoromethylating Agent for Catalytic Difluoromethylation

D5390, I0079

Reference


Application
Iron/dppbz-catalyzed Decarboxylative Couplings of Active Esters

I0079

In a screwed-capped vial active ester (0.1 mmol), Fe(acac)3 (0.005 – 0.04 mmol) and dppbz (0.006 – 0.048 mmol) are weighed. The vial is then sealed, evacuated and back-filled with Ar. Then, 0.5 mL of distilled THF is added. The mixture is stirred for 5 minutes under Ar and diarylzinc reagent in THF (ca. 0.3 mol/L, 0.15 – 0.25 mmol) is added in one portion at 0 - 25 °C to the mixture and stirred at the same temperature for 1 h. After this time, the reaction is quenched with 1 mol/L HClaq, sat. NH4Claq or H2O and diluted with diethyl ether. The organic layer is separated and dried over Na2SO4 anhydrous, filtered and evaporated to dryness. Pure products are obtained after column chromatography or preparative TLC.

References


Application
Iron-Catalyzed ortho-Alkylation of Carboxamides

I0079

Typical procedure (R = benzyl): To Fe(acac)3 (17.1 mg, 0.05 mmol), dppe (29.9 mg, 0.075 mmol), and 3-methyl-N-(quinolin-8-yl)benzamide (131 mg, 0.5 mmol) are added THF (4 mL), and benzyl chloride (190 mg, 1.5 mmol). The mixture is then placed in an oil bath at 65 °C and PhMgBr (16% in THF, ca. 1 mol/L) (0.6 mL, 0.6 mmol) is added in a single portion. Upon completion of PhMgBr addition, the reaction mixture is stirred at 65 °C for 1 min. Then PhMgBr (16% in THF, ca. 1 mol/L) (1.3 mL, 1.3 mmol) is added dropwise at 65 °C for 9 min. The reaction mixture is stirred at 65 °C for 1 min and brought to rt. Subsequently the reaction mixture is quenched with a saturated solution of ammonium chloride (535 mg, 0.01 mol) and extracted with dichloromethane (3 x 3 mL). The combined organic extracts are dried over MgSO4, filtered and concentrated to give a residue. The residue is purified by silica gel flash chromatography (eluent: hexanes/EtOAc = 20:1) to give 2-benzyl-5-methyl-N-(quinolin-8-yl)benzamide (175 mg, 99% yield) as a white solid.

References


Application
Efficient Fe/Cu Co-Catalyzed C-N Cross-Coupling Reaction

Typical procedure (Entry 1): A Schlenk tube is charged with p-anisidine (92.4 mg), K2CO3 (138 mg), Fe(acac)3 (34.4 mg), and Cu(OAc)2· H2O (20 mg). Under a nitrogen atmosphere, 4-bromotoluene (85.5 mg) is added followed by dry DMF (0.8 mL). The reaction mixture is then heated to 135 °C, and stirred for 20 h. The mixture is cooled to room temperature and diluted with diethyl ether. The resulting suspension is filtered through a celite pad and the filtrate is concentrated. The residue is purified by column chromatography on silica gel (eluent: petroleum ether/ethyl acetate) to give 4-methoxy-N-p-tolylaniline (98.1 mg, 92 %).

References


Application
Iron-Catalyzed Cross-Coupling Reaction

Reference


PubMed Literature


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