Published TCIMAIL newest issue No.201
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 1271-66-5 | Product Number: D4100
Dimethyltitanocene (5% in Tetrahydrofuran/Toluene)
×
Purity:
Synonyms:
- Bis(cyclopentadienyl)dimethyltitanium (5% in Tetrahydrofuran/Toluene)
- Petasis Reagent (5% in Tetrahydrofuran/Toluene)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 25G |
90,00 €
|
7 | 10 |
|
|
| 100G |
285,00 €
|
2 | 2 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
Supplemental Product Information:
This product cannot be shipped to Russia and Turkey.
| Product Number | D4100 |
| Molecular Formula / Molecular Weight | C__1__2H__1__6Ti = 208.13 |
| Physical State (20 deg.C) | Liquid |
Storage Temperature 
|
Frozen (<0°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive,Heat Sensitive |
| CAS RN | 1271-66-5 |
| Reaxys Registry Number | 14221496 |
| PubChem Substance ID | 135727045 |
| MDL Number | MFCD02093882 |
Specifications
| Appearance | Orange to Red clear liquid |
| Concentration(HNMR) | 5.0 to 5.7 w/w% |
| NMR | confirm to structure |
Properties (reference)
| Specific Gravity (20/20) | 0.89 |
| Refractive Index | 1.49 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H332 : Harmful if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. H371 : May cause damage to organs. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H351 : Suspected of causing cancer. H335 : May cause respiratory irritation. H361d : Suspected of damaging the unborn child. H336 : May cause drowsiness or dizziness. H304 : May be fatal if swallowed and enters airways. H225 : Highly flammable liquid and vapour. |
| Precautionary Statements | P260 : Do not breathe mist or vapours. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P331 : Do NOT induce vomiting. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. |
Related Laws:
Transport Information:
| UN Number | UN1993 |
| Class | 3 |
| Packing Group | II |
| HS Number | 3822190090 |
Application
Methylenations of Carbonyl Compounds
References
- N. A. Petasis, E. I. Bzowej, J. Am. Chem. Soc. 1990, 112, 6392.
- N. A. Petasis, S.-P. Lu, E. I. Bzowej, D.-K. Fu, J. P. Staszewski, I. Akritopoulou-Zanze, M. A. Patane, Y.-H. Hu, Pure Appl. Chem. 1996, 68, 667.
Application
Ring-Closing Metathesis Using Petasis Reagent
Reference
- Olefin Metathesis in Cyclic Ether Formation. Direct Conversion of Olefinic Esters to Cyclic Enol Ethers with Tebbe-Type Reagents
PubMed Literature
Documents
Product Articles
[TCIMAIL No.155] Short Topic: More ways to use reagents | Ring-Closing Metathesis Using Tebbe or Petasis Reagent
Product Documents (Note: Some products will not have analytical charts available.)
Enter TCI Product Number
Enter KISHIDA Product Number
4-5 alphanumeric characters before the hyphen
7 alphanumeric characters
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
• The requested SDS is not available.
Specifications
The requested specifications are not available.
Please Contact Us for more information.
The requested specifications are not available.
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Incorrect Lot Number. Please input only the 7 alphanumeric characters.
• Please check that the lot number you have entered is correct. It is 4-5 alphanumeric characters before the hyphen. In particular, please check O (letter) or 0 (number) and I (letter) or 1 (number).
• If your information is correct and you are still not able to view the requested certificates, Please Contact Us for more information.
• Please check that the lot number you have entered is correct. It is 7 alphanumeric characters. In particular, please check O (letter) or 0 (number) and I (letter) or 1 (number).
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Incorrect Lot Number. Please input only the 7 alphanumeric characters.
The requested analytical chart is not available. Sorry for the inconvenience.