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Published TCIMAIL newest issue No.198
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CAS RN: 1000668-90-5 | Product Number: M2476
2,2'-(Methylimino)bis(N,N-di-n-octylacetamide)
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Purity: >95.0%(GC)(T)
Synonyms:
- MIDOA
Product Documents:
| Size | Unit Price | Belgium | Japan* |
|---|---|---|---|
| 1ML |
118,00 €
|
1 | 4 |
| 5ML |
404,00 €
|
2 | 8 |
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | M2476 |
Purity / Analysis Method 
|
>95.0%(GC)(T) |
| Molecular Formula / Molecular Weight | C__3__7H__7__5N__3O__2 = 594.03 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 1000668-90-5 |
| Reaxys Registry Number | 11271972 |
| PubChem Substance ID | 253662579 |
Specifications
| Appearance | Light yellow to Yellow to Orange clear liquid |
| Purity(GC) | min. 95.0 % |
| Purity(Nonaqueous Titration) | min. 95.0 % |
| NMR | confirm to structure |
Properties (reference)
| Flash point | 203 °C |
| Specific Gravity (20/20) | 0.90 |
| Refractive Index | 1.47 |
GHS
Related Laws:
Transport Information:
| HS Number | 2924190090 |
Application
A New Efficient Extractant for Metal Ions Classified Soft Acids
2,2'-(Methylimino)bis(N,N-di-n-octylacetamide) (MIDOA or MIDAA) is a new efficient metal extractant, developed by Sasaki et al.1) MIDOA is highly lipophilic and ready to use in the HNO3(aq.)–n-dodecane extraction system. MIDOA has high extractability for metal ions classified soft acids because of the nitrogen donor atom centered in the backbones, complementary of hard ions extractant TODGA [O0523]. Therefore, the distribution ratio for Tc(VII) is extremely high. In addition, Cr(VI), Re(VII), Mo(VI), W(VI), Pd(II) and Pu(IV) are well extracted by MIDOA.1,2)
*This product receives a license of invention of the Japan Atomic Energy Agency (JAEA) and Ibaraki University
(Japan Kokai Tokkyo Koho JP2011-001809 (2011), JP2012-144448 (2012) and Fr Pat. 2970251 (2012)).
References
- 1)The first report of a novel extractant, MIDOA
- 2)Reports on the extraction ability of MIDOA
- a)Y. Sasaki, M. Ozawa, T. Kimura, K. Ohashi, Solvent Extr. Ion Exch. 2009, 27, 378.
- b)Y. Sasaki, Y. Sugo, M. Saeki, Y. Morita, A. Ohashi, Solvent Extr. Res. Dev. Jpn. 2011, 18, 69.
- c)Y. Sasaki, Y. Tsubata, Y. Kitatsuji, Y. Sugo, N. Shirasu, Y. Morita, T. Kimura, Solvent Extr. Ion Exch. 2013, 31, 401.
- d)M. Saeki, Y. Sasaki, A. Nakai, A. Ohashi, D. Banerjee, A. C. Scheinost, H. Foerstendorf, Inorg. Chem. 2012, 51, 5814.
- a)Y. Sasaki, M. Ozawa, T. Kimura, K. Ohashi, Solvent Extr. Ion Exch. 2009, 27, 378.
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