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Pyridinesulfinates, Pyrimidinesulfinates [Cross-coupling Reaction using Transition Metal Catalysts]

Pyridinesulfinates ― Surrogates of Pyridineboronates
 Pyridine-2-sulfinates and pyrimidine-2-sulfinates can be utilized in Suzuki-Miyaura cross coupling reagents as replacements for pyridine-2-boronic acids and pyrimidine-2-boronic acids, which are difficult to prepare. These reagents are tolerated by ketone, ester, trifluoromethyl, and other functional groups.1,2) Also the cross-coupling reaction with Grignard reagents proceeds without transition metals.3) It has been reported that these reagents are applied to late-stage modifications in drug discovery, and ligand syntheses for catalytic reactions.
Cross-coupling using Pyridine-2-sulfinates, Pyrimidine-2-sulfinates


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Product Number O0541
CAS RN 2188151-68-8
Purity / Analysis Method: >97.0%(T)(HPLC)

Product Number O0539
CAS RN 116008-37-8
Purity / Analysis Method: >95.0%(T)(HPLC)

Product Number O0546
CAS RN 2098851-48-8
Purity / Analysis Method: >98.0%(T)(HPLC)

Product Number O0533
CAS RN 24367-66-6
Purity / Analysis Method: >95.0%(T)

Product Number:   O0541 | Purity / Analysis Method:   >97.0%(T)(HPLC)

Product Number:   O0539 | Purity / Analysis Method:   >95.0%(T)(HPLC)

Product Number:   O0546 | Purity / Analysis Method:   >98.0%(T)(HPLC)

Product Number:   O0533 | Purity / Analysis Method:   >95.0%(T)