Maximum quantity allowed is 999
Please select the quantity
CAS RN: 866081-62-1 | Product Number: B5301
(R,R)-(-)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
Purity: >98.0%(HPLC)
Synonyms:
- (R,R)-QuinoxP*
Documents:
Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH | Shipping Information |
---|---|---|---|---|---|
100MG |
¥21,600
|
2 | 7 | Contact Us |
* Available Stock: Prompt shipment (for products) in Saitama/Hyogo warehouse. Stock In Other WH: Shipment in about 2-3 Business Days from Saitama warehouse. Please contact us
if you need further information.
* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Product Number | B5301 |
Purity / Analysis Method | >98.0%(HPLC) |
Molecular Formula / Molecular Weight | C__1__8H__2__8N__2P__2 = 334.38 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Air Sensitive |
Packaging and Container | 100MG-Glass Bottle with Plastic Insert (View image) |
CAS RN | 866081-62-1 |
Reaxys Registry Number | 10182166 |
PubChem Substance ID | 354334700 |
MDL Number | MFCD10565649 |
Specifications
Appearance | Light yellow to Brown powder to crystal |
Purity(HPLC) | min. 98.0 area% |
Melting point | 100.0 to 104.0 °C |
Specific rotation [a]20/D | -48.0 to -53.0 deg(C=1, CHCL3) |
Properties (reference)
Melting Point | 102 °C |
Specific Rotation | -52° (C=1,CHCl3) |
GHS
Pictogram | |
Signal Word | Warning |
Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H413 : May cause long lasting harmful effects to aquatic life. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
Application
Dynamic Kinetic Resolution using a Palladium / QuinoxP* Complex
References
- 1)A Rational Pre-catalyst Design for Bis-Phosphine Mono-oxide Palladium Catalyzed Reactions
- 2)Enantioselective Synthesis of Hemiaminals via Pd-Catalyzed C?N Coupling with Chiral Bisphosphine Mono-oxides
- 3)Searching for Practically Useful P-Chirogenic Phosphine Ligands
Application
Copper Catalyzed Asymmetric Conjugate Addition
References
- Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones
- Searching for Practically Useful P-Chirogenic Phosphine Ligands
Application
Rhodium Catalyzed Enantioselective Hydroacylation of Acrylamide Derivatives
References
- Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes
- Searching for Practically Useful P-Chirogenic Phosphine Ligands
Application
Ruthenium Complex Catalyzed Asymmetric Hydrogenation
References
- t-Bu-QuinoxP* Ligand:? Applications in Asymmetric Pd-Catalyzed Allylic Substitution and Ru-Catalyzed Hydrogenation
- Searching for Practically Useful P-Chirogenic Phosphine Ligands
PubMed Literature
Articles/Brochures
Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.