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CAS RN: 1868173-29-8 | Product Number: F1111
[4-Fluoro-3-(trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium p-Toluenesulfonate
iodonium p-Toluenesulfonate](/medias/F1111.jpg?context=bWFzdGVyfHJvb3R8MTYyNzh8aW1hZ2UvanBlZ3xhR1JtTDJoaFppODRPVE0xTWpJd05UYzJNamcyTDBZeE1URXhMbXB3Wnd8ZTU5ZmFlOTU1M2I3ODNkMmNhMmIwMTcwYTNlOWU4YTY0ZDAzNmQxYTY3MWRiODUwMjYyMGQ1ZGQ4NmFhNDZhMA "[4-Fluoro-3-(trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium p-Toluenesulfonate")
iodonium p-Toluenesulfonate](/medias/F1111.jpg?context=bWFzdGVyfHJvb3R8NTU0NjZ8aW1hZ2UvanBlZ3xhR0pqTDJoa05DODRPVEl4T0RJNU5EQTROems0TDBZeE1URXhMbXB3Wnd8NDdiM2VjZTIyYzk4MDZlMTVkNjE3ZGQxMTY4N2QyNGVkODg0YWIxMTkzYjg0NjZhYmRlOTM2MDI2ODVlYTRkMQ "[4-Fluoro-3-(trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium p-Toluenesulfonate")
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iodonium p-Toluenesulfonate](/_ui/responsive/theme-tci/images/missing_product_zoom.webp "[4-Fluoro-3-(trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium p-Toluenesulfonate")
Purity: >97.0%(HPLC)
Synonyms:
- [4-Fluoro-3-(trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium Tosylate
Product Documents:
| Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
Shipping Information
|
|---|---|---|---|---|---|
| 200MG |
¥8,800
|
5 | 11 | It can be shipped in about 2 weeks after ordering | |
| 1G |
¥29,300
|
9 | 1 | 8 |
* Available Stock: Prompt shipment (for products) in Saitama/Hyogo warehouse. Stock In Other WH: Shipment in about 2-3 Business Days from Saitama warehouse. Please contact us
if you need further information.
* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Supplemental Product Information:
This product is commercialized in partnership with Dr. Stuart and PSU.
| Product Number | F1111 |
Purity / Analysis Method 
|
>97.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__2__3H__2__1F__4IO__6S = 628.37 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Refrigerated (0-10°C) |
| Condition to Avoid | Light Sensitive,Heat Sensitive |
| Packaging and Container
|
200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 1868173-29-8 |
| PubChem Substance ID | 354334166 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(HPLC) | min. 97.0 %(total of Ion-Pair) |
| NMR | confirm to structure |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
Application
Asymmetric Diaryliodonium Tosylates Useful for Metal-free Arylations
References
- 1)Aryl(2,4,6-trimethoxyphenyl)iodonium Salts as Reagents for Metal-Free Arylation of Carbon and Heteroatom Nucleophiles
- 2)Unsymmetrical Aryl(2,4,6-trimethoxyphenyl)iodonium Salts: One-Pot Synthesis, Scope, Stability, and Synthetic Studies
- 3)Single-step syntheses of no-carrier-added functionalized [18F]fluoroarenes as labeling synthons from diaryliodonium salts
Application
Hypervalent iodine compounds usable for arylating reactions
Stuart et al. have designed and synthesized some diaryl-substituted hypervalent iodine compounds having a 1,3,5-trimethoxybenzene (TMB) moiety and an aromatic ring. In these compounds, the TMB moiety acts as a leaving group so that the other aromatic ring can be used for the aryl group introduction. Various functional groups such as cyano, nitro, fluoro, or chloro substituted aromatic TMB hypervalent iodine compounds have been reported so far. It is expected to use these compounds for transition-metal-free arylations.
References
- Unsymmetrical Aryl(2,4,6-trimethoxyphenyl)iodonium Salts: One-Pot Synthesis, Scope, Stability, and Synthetic Studies
PubMed Literature
Documents
Product Articles
[Product Highlights] Asymmetric Diaryliodonium Tosylates Useful for Metal-free Arylations
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