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CAS RN: 496-15-1 | Product Number: I0033
Indoline
Purity: >98.0%(GC)(T)
Chemical Substance Law (ENCS):
5-3364
Synonyms:
- 2,3-Dihydroindole
Documents:
Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
---|---|---|---|---|
25ML |
¥4,200
|
≥40 | 15 | ≥40 |
250ML |
¥25,400
|
8 | Contact Us | Contact Us |
Available Stock: Prompt shipment (for products) in Saitama/Hyogo warehouse. Stock in other WH: 2-3 Business Days
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* Please contact us if you need further information.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Product Number | I0033 |
Purity / Analysis Method | >98.0%(GC)(T) |
Molecular Formula / Molecular Weight | C__8H__9N = 119.17 |
Physical State (20 deg.C) | Liquid |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Light Sensitive,Air Sensitive |
CAS RN | 496-15-1 |
Reaxys Registry Number | 111915 |
PubChem Substance ID | 87571442 |
SDBS (AIST Spectral DB) | 1358 |
MDL Number | MFCD00005705 |
Specifications
Appearance | Colorless to Orange to Green clear liquid |
Purity(GC) | min. 98.0 % |
Purity(Nonaqueous Titration) | min. 98.0 % |
Properties (reference)
Boiling Point | 231 °C |
Flash point | 93 °C |
Specific Gravity (20/20) | 1.07 |
Refractive Index | 1.59 |
GHS
Pictogram |
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Signal Word | Warning |
Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H227 : Combustible liquid. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P403 + P235 : Store in a well-ventilated place. Keep cool. |
Related Laws:
Chemical Substance Law (ENCS) |
5-3364 |
Fire Defense Law | Group-4-3-III |
RTECS# | NL6906300 |
Transport Information:
Application
Catalytic Formylation Using Indoline
Experimental procedure:
Alkenylboronic acids (0.12 mmol, 1.2 eq.) and glyoxylic acid monohydrate (0.1 mmol, 1.0 eq., 9.2 mg) are placed in a flask. Acetonitrile (1.0 mL) is injected into the vial and then indoline (0.03 mmol, 3.4 µL) is added. The mixture is stirred at room temperature for 24 h exposed to air. After stirred for 24 h, the residue is purified by column chromatography (SiO2, hexanes:EtOAc) to provide the corresponding compounds.
Alkenylboronic acids (0.12 mmol, 1.2 eq.) and glyoxylic acid monohydrate (0.1 mmol, 1.0 eq., 9.2 mg) are placed in a flask. Acetonitrile (1.0 mL) is injected into the vial and then indoline (0.03 mmol, 3.4 µL) is added. The mixture is stirred at room temperature for 24 h exposed to air. After stirred for 24 h, the residue is purified by column chromatography (SiO2, hexanes:EtOAc) to provide the corresponding compounds.
References
- Synthesis of Aldehydes by Organocatalytic Formylation Reactions of Boronic Acids with Glyoxylic Acid
PubMed Literature
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