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CAS RN: 7550-35-8 | Product Number: L0210

Lithium Bromide

Purity: >99.0%(T)
Chemical Substance Law (ENCS):   1-110
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Product Number L0210
Purity / Analysis Method >99.0%(T)
Molecular Formula / Molecular Weight LiBr = 86.84 
Physical State (20 deg.C) Solid
CAS RN 7550-35-8
PubChem Substance ID 87561397
Merck Index (14) 5526
MDL Number


Appearance White powder to crystal
Purity(Argentometric Titration) min. 99.0 %
Properties (reference)
Melting Point 549 °C
Solubility in water Completely soluble
Solubility (very soluble in) Alcohol
Solubility (soluble in) Acetone
Pictogram Pictogram
Signal Word Warning
Hazard Statements H302 : Harmful if swallowed.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H402 : Harmful to aquatic life.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P273 : Avoid release to the environment.
P270 : Do not eat, drink or smoke when using this product.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
Related Laws:
Chemical Substance Law (ENCS) 1-110
RTECS# OJ5755000
Transport Information:
Sodium- and Ammonia-Free Birch Reduction by Electroreduction

Experimental procedure: An electrochemical cell with magnesium as the anode and galvanized steel wire as the cathode is added to a substrate (0.1 mmol, 1.0 eq.), 1,3-dimethylurea (0.3 mmol, 3.0 eq), tripyrrolidinophosphine oxide (1.0 mmol, 10 eq.), and 1.5 mol/L THF solution of LiBr (500 µL). The reaction mixture is added to THF (3 mL) and is purged with argon. Electrolysis is initiated at a cell ampere of 10 mA at room temperature. After full consumption of substrate, the cell is washed with diethyl ether, and solvent is removed in vacuo. To residue solution is added diethyl ether and solution of Rochelle salt, and then is stirred until two clear layers formed. The organic layer is separated, and the aqueous layer is extracted twice with diethyl ether. The combined organic layers are dried over anhydrous MgSO4. After the organics removed in vacuo, the residue is purified by short silica colum (elution: ethyl acetate) to give product.


PubMed Literature


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