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CAS RN: 75-16-1 | Product Number: M0785

Methylmagnesium Bromide (35% in Ethyl Ether, ca. 3mol/L)


Purity:
Chemical Substance Law (ENCS):   2-3468 |Narcotic or Psychotropic Raw Material
Synonyms:
Documents:
250G
¥13,500
4   12   ≥20 
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Note:

【Disposal】After dilution with twice the volume of toluene, ethyl acetate is added dropwise into the Grignard solution under ice cooling, then quenched by 10% ammonium chloride solution. The resulting organic and aqueous layers after a separation procedure are disposed. The aqueous layer should be neutralized before disposal.The above is only one example of inactivation and following the disposal procedures in our laboratory. You should take sufficient safety measures for proper disposal, observing the amount and condition of waste materials. In addition, you also need to comply with your local government regulations.

Product Number M0785
Molecular Formula / Molecular Weight CH__3BrMg = 119.24  
Physical State (20 deg.C) Liquid
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 75-16-1
Reaxys Registry Number 3909313
PubChem Substance ID 87572784
MDL Number

MFCD00000041

Specifications
Concentration(sec Butanol method) 35.0 to 38.5 w/w%
Properties (reference)
Flash point -40 °C
GHS
Pictogram Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H302 : Harmful if swallowed.
H314 : Causes severe skin burns and eye damage.
H361 : Suspected of damaging fertility or the unborn child.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H225 : Highly flammable liquid and vapor.
H260 : In contact with water releases flammable gases which may ignite spontaneously.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P223 : Do not allow contact with water.
P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P202 : Do not handle until all safety precautions have been read and understood.
P240 : Ground/bond container and receiving equipment.
P231 + P232 : Handle under inert gas. Protect from moisture.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P201 : Obtain special instructions before use.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P335 + P334 : Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages.
P308 + P313 : IF exposed or concerned: Get medical advice/ attention.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P402 + P404 : Store in a dry place. Store in a closed container.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P405 : Store locked up.
Related Laws:
Chemical Substance Law (ENCS) 2-3468
ISHL Organic Solvents Class 2
Narcotics and Psychotropics Control Law Narcotic or Psychotropic Raw Material
Fire Defense Law Group-4-S-I
Transport Information:
UN Number UN1928
Class 4.3 / 3
Packing Group I
TCIMAIL
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