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CAS RN: 68478-92-2 | Product Number: P2075

Platinum(0) - 1,3-Divinyltetramethyldisiloxane Complex (19.0-21.5% as Pt) (contains 1,3-Divinyltetramethyldisiloxane)

  • Karstedt Catalyst (19.0-21.5% as Pt) (contains 1,3-Divinyltetramethyldisiloxane)
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Product Number P2075
Physical State (20 deg.C) Liquid
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive
CAS RN 68478-92-2
Reaxys Registry Number 11327506
MDL Number


Appearance Light yellow to Yellow to Green clear liquid
Content(Platinum) 19.0 to 21.5 %
Properties (reference)
Flash point 28 °C
Specific Gravity (20/20) 1.2
Pictogram Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H413 : May cause long lasting harmful effects to aquatic life.
H226 : Flammable liquid and vapor.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P273 : Avoid release to the environment.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P403 + P235 : Store in a well-ventilated place. Keep cool.
Related Laws:
Fire Defense Law Group-4-2-III
Transport Information:
UN Number UN1993
Class 3
Packing Group III
Karstedt Catalyst: A Useful Platinum Catalyst for Hydrosilylation

Experimental procedure: dimethyl-2-thienylsilane (32 mg, 0.22 mmol) is added dropwise to a solution of Karstedt catalyst (0.1 M in xylenes,9 µL,0.0009 mmol) and tert-Bu3P (1 µL,0.003 mmol) in THF (0.7 mL), and the mixture is stirred for 30 min at rt. A solution of (E)-5-(tetrahydropyran-2-yloxy)pent-3-en-1-yne (30 mg,0.18 mmol) in THF (1 mL) is then added over 10 min and the reaction mixture is stirred for 10 h at rt. The solvent is removed under vacuum and the crude is purified by column chromatography (SiO2, hexane/AcOEt) to afford 1 (92% yield).


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