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CAS RN: 1259070-80-8 | Product Number: R0196

Ru(II)-(S)-Pheox Catalyst


Purity:
Deleterious substance
Synonyms:
  • Tetrakis(acetonitrile)[2-[(4S)-4,5-dihydro-4-phenyl-2-oxazolyl-N]phenyl]ruthenium(II) Hexafluorophosphate
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Product Number R0196
Molecular Formula / Molecular Weight C__2__3H__2__4F__6N__5OPRu = 632.51 
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive
CAS RN 1259070-80-8
Reaxys Registry Number 21095236
PubChem Substance ID 354335346
Specifications
Appearance Light yellow to Amber to Dark green powder to crystal
Elemental analysis(Nitrogen) 10.50 to 11.50 %
Specific rotation [a]20/D +235 ~ +245 deg(C=0.1, CH3CN)
Properties (reference)
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/doctor if you feel unwell.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
Related Laws:
Poisonous or Deleterious Deleterious substance
Transport Information:
Application
Ru(II)-(S)-Pheox: Chiral Ru(II)-Catalyst for Enantioselective Cyclopropanation

Ru(II)-(S)-Pheox catalyst is a novel phenyloxazoline-Ru(II) complex, developed by Iwasa, et al. The catalyst shows highly enantioselective cyclopropanation of various olefins using diazoacetates1-6,8) or diazomethylphosphonates7,8). The catalyst is a promising reagent for optically active cyclopropane derivatives which are present in a number of medicinally relevant compounds. In addition, the catalyst is also used for an enantioselective Si–H insertion reaction of α-diazo esters.9) (Related products: (S)-Pheox [D5368])

References


PubMed Literature


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