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CAS RN: 811-68-7 | Product Number: S0977

Silver(I) Trifluoromethanethiolate

Purity: >95.0%(T)
Deleterious substance
  • Trifluoromethanethiol Silver(I) Salt
≥20  19   ≥20 
≥20  Contact Us Contact Us
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Product Number S0977
Purity / Analysis Method >95.0%(T)
Molecular Formula / Molecular Weight CAgF__3S = 208.93  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive
Packaging and Container 1G-Glass Bottle with Plastic Insert (View image)
CAS RN 811-68-7
Reaxys Registry Number 4151922
PubChem Substance ID 354333285
MDL Number


Appearance White to Light yellow to Light red powder to crystal
Purity(Precipitation Titration) min. 95.0 %
Properties (reference)
Solubility in water Insoluble
Solubility (slightly sol. in) Methanol
Related Laws:
Poisonous or Deleterious Deleterious substance
Transport Information:
Trifluoromethylthiolating Agent Usable for Direct Dehydroxytrifluoromethylthiolation of Alcohols


Experimental procedure3): AgSCF3 (251 mg, 1.2 mmol, 3.0 eq.) and TBAI (1330 mg, 3.6 mmol, 9.0 eq.) are combined in a Schlenk tube. The tube is mounted with a reflux condenser and backfilled with N2, then toluene (4.0 mL) and alcohol (0.4 mmol, 1.0 eq.) are added. The tube is placed into a preheated oil bath at 80 °C with vigorous stirring. After 10 h, the reaction mixture is cooled to room temperature and filtered through a plug of silica (eluted with EtOAc). The filtrate is concentrated, and the product is purified by column chromatography on silica gel to give the desired product.


PubMed Literature

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