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CAS RN: 26042-63-7 | Product Number: S0981

Silver Hexafluorophosphate

Purity: >98.0%(T)
Deleterious substance
2   11   ≥20 
≥20  5   ≥20 
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Product Number S0981
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight AgPF__6 = 252.83  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Hygroscopic
CAS RN 26042-63-7
Reaxys Registry Number 13607729
PubChem Substance ID 354333698
MDL Number


Appearance White to Orange to Green powder to crystal
Purity(Precipitation Titration) min. 98.0 %
Properties (reference)
Melting Point 102 °C(dec.)
Maximum Absorption Wavelength 413(CHCl3) nm
Solubility in water Soluble
Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
H290 : May be corrosive to metals.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P260 : Do not breathe dusts or mists.
P234 : Keep only in original container.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P390 : Absorb spillage to prevent material damage.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P406 : Store in corrosive resistant container with a resistant inner liner.
P405 : Store locked up.
Related Laws:
PRTR Law (New Specific Chemical) Class 1 Designated Chemical Substances
Poisonous or Deleterious Deleterious substance
Transport Information:
UN Number UN3260
Class 8
Packing Group II
A C-Arylation of N-Tosyl Aziridines


Experimental procedure: A mixture of 1 (1 mmol, 273 mg), anisole (2 mmol, 100 µL) and AgPF6 (0.02 mmol, 5 mg) in 3 mL of dry dichloroethane are stirred at 30 - 35 °C. Then the reaction mixture is diluted with water (5 mL) and extracted with dichloroethane (5 mL). The combined organic layers are dried over anhydrous sodium sulfate, concentrated in vacuo and the resulting product is purified by column chromatography on silica gel (ethyl acetate : petroleum ether = 1 : 10) to afford 2 (305 mg, 80% yield).


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