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CAS RN: 14694-95-2 | Product Number: T0931

Tris(triphenylphosphine)rhodium(I) Chloride


Purity: >98.0%(T)
Synonyms:
  • Chlorotris(triphenylphosphine)rhodium(I)
  • Wilkinson Catalyst
Documents:
1G
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Product Number T0931
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__5__4H__4__5ClP__3Rh = 925.23 
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive
Packaging and Container 1G-Glass Bottle with Plastic Insert (View image)
CAS RN 14694-95-2
Reaxys Registry Number 14664394
PubChem Substance ID 87576749
SDBS (AIST Spectral DB) 5193
Merck Index (14) 9758
MDL Number

MFCD00010016

Specifications
Appearance Orange to Brown to Dark red powder to crystal
Purity(Argentometric Titration) min. 98.0 %
Properties (reference)
Solubility in water Insoluble
Solubility (soluble in) Chloroform,Benzene,dichloromethane,Toluene
Solubility (very slightly) Methanol
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
Application
Trimethylsilylation of Alcohols using TMS Reagents

T0931

Reference

  • Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


Application
Wilkinson’s Catalyst: a Homogeneous Catalyst for Hydrogenation

References


Application
Rh-catalyzed Coupling Reaction between THF and Olefins

Reference


PubMed Literature


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