Hydrozirconation

References

• 1) Synthesis and rearrangement of alkylzirconium(IV) complexes
•  a) Reaction of the complexes with electrophiles
  •  D. W. Hart, J. Schwartz, J. Am. Chem. Soc. 1974, 96, 8115.
•  b) Oxidation of the complexes to alcohols
  •  T. F. Blackburn, J. A. Labinger, J. Schwartz, Tetrahedron Lett. 1975, 3041.
•  c) Oxidative homologation of olefins via CO insertion into C-Zr bond
  •  C. A. Bertelo, J. Schwartz, J. Am. Chem. Soc. 1975, 97, 228.
• 2) Stereospecific and regioselective functionalization of alkylacetylenes
  •  D. W. Hart, T. F. Blackburn, J. Schwartz, J. Am. Chem. Soc. 1975, 97, 679.
• 3) Other applications
•  a) Synthesis of long-chain primary alkyl compounds
  •  T. Gibson, L. Tulich, J. Org. Chem. 1981, 46, 1821.
•  b) Conversion of alkynes and alkenes into one-carbon homologated aldehydes
  •  E. Negishi, D. R. Swanson, S. R. Miller, Tetrahedron Lett. 1988, 29, 1631.

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