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CAS RN: 13292-87-0 | Product Number: D1843
Dimethyl Sulfide Borane

Purity: >90.0%(T)
Synonyms:
- Borane - Dimethyl Sulfide Complex
- BMS
- Methyl Sulfide Borane
Product Documents:
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* The storage conditions are subject to change without notice.
* The storage conditions are subject to change without notice.
Supplemental Product Information:
25mL and 100mL bottle of this product are attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".
Product Number | D1843 |
Purity / Analysis Method | >90.0%(T) |
Molecular Formula / Molecular Weight | C__2H__6S·BH__3 = 75.96 |
Physical State (20 deg.C) | Liquid |
Storage Temperature | Refrigerated (0-10°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Air Sensitive,Moisture Sensitive,Heat Sensitive |
Packaging and Container | 100ML-DualSeal Bottle (View image), 25ML-DualSeal Bottle (View image) |
CAS RN | 13292-87-0 |
Reaxys Registry Number | 3663489 |
PubChem Substance ID | 87568309 |
MDL Number | MFCD00013189 |
Specifications
Appearance | Colorless to Light yellow clear liquid |
Purity(Neutralization titration) | min. 90.0 % |
NMR | confirm to structure |
Properties (reference)
Flash point | 18 °C |
Specific Gravity (20/20) | 0.80 |
Refractive Index | 1.46 |
GHS
Pictogram |
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Signal Word | Danger |
Hazard Statements | H318 : Causes serious eye damage. H225 : Highly flammable liquid and vapor. H260 : In contact with water releases flammable gases which may ignite spontaneously. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P223 : Do not allow contact with water. P240 : Ground/bond container and receiving equipment. P231 + P232 : Handle under inert gas. Protect from moisture. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P335 + P334 : Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P402 + P404 : Store in a dry place. Store in a closed container. P403 + P235 : Store in a well-ventilated place. Keep cool. |
Related Laws:
RTECS# | PV5080000 |
Transport Information:
UN Number | UN3399 |
Class | 4.3 / 3 |
Packing Group | I |
H.S.code* | 2930.90-900 |
Application
A Stereoselective Hydroamination Transform To Access Polysubstituted Indolizidines
Reference
Application
Hydroboration
References
- S. Saito, T. Hasegawa, M. Inaba, R. Nishida, T. Fujii, S. Nomizu, T. Moriwake, Chem. Lett. 1984, 1389.
- L. M. Braun, R. A. Braun, H. R. Crissman, M. Opperman, R. M. Adams, J. Org. Chem. 1971, 36, 2388.
- C. F. Lane, J. Org. Chem. 1974, 39, 1437.
- R. O. Hutchins, F. Cistone, Org. Prep. Proced. Int. 1981, 13, 225.
- C. F. Lane, J. J. Daniels, Org. Synth. Coll. Vol. 1988, 6, 719.
- H. C. Brown, J. V. N. Vara Prasad, S-H. Zee, J. Org. Chem. 1986, 51, 439.
PubMed Literature
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