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CAS RN: 15629-92-2 | Product Number: B1313
[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride
![Thumbnail of [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride](/medias/B1313.jpg?context=bWFzdGVyfHJvb3R8MTg2MDR8aW1hZ2UvanBlZ3xhRGxoTDJobU9TODRPVE16TXpJeE1qRXhPVE0wTDBJeE16RXpMbXB3Wnd8YmUwMDc3YzRkNjIyMzkzMjNlMWIwYjQ3Zjc5YzJmYjNkYTRmMzA5YTc4NTAxODNhNjM2MzJhZWQ0OWQ0ZjgwZA "[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride")
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Purity: >98.0%(T)
Synonyms:
- [1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
- Dichloro[1,3-bis(diphenylphosphino)propane]nickel(II)
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
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|---|---|---|---|---|---|
| 5G |
$77.00
|
14 | ≥60 | Contact Us | |
| 25G |
$271.00
|
≥40 | 30 | Contact Us |
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| Product Number | B1313 |
Purity / Analysis Method 
|
>98.0%(T) |
| Molecular Formula / Molecular Weight | C__2__7H__2__6Cl__2NiP__2 = 542.05 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| CAS RN | 15629-92-2 |
| Reaxys Registry Number | 13876693 |
| PubChem Substance ID | 87564245 |
| MDL Number | MFCD00015318 |
Specifications
| Appearance | Orange to Brown to Dark red powder to crystal |
| Purity(Chelometric Titration) | min. 98.0 % |
| Purity(Argentometric Titration) | min. 98.0 % |
| IR | confirm to structure |
Properties (reference)
| Melting Point | 213 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 : May cause cancer. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P272 : Contaminated work clothing should not be allowed out of the workplace. P260 : Do not breathe dust. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P201 : Obtain special instructions before use. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P342 + P311 : If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P304 + P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P405 : Store locked up. |
Related Laws:
Transport Information:
| H.S.code* | 2931.49-000 |
Application
Catalyst for Controlled Coupling Polymerization
References
- Chain-growth synthesis of polyfluorenes with low polydispersities, block copolymers of fluorene, and end-capped polyfluorenes: Toward new optoelectronic materials
- Regioregular, head-to-tail coupled poly(3-alkylthiophenes) made easy by the GRIM method:? Investigation of the reaction and the origin of regioselectivity
Application
Kumada-Tamao-Corriu Coupling
References
PubMed Literature
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