text.skipToContent text.skipToNavigation

Maximum quantity allowed is 999

Please select the quantity

CAS RN: 502964-52-5 | Product Number: N1060


Purity: >97.0%(HPLC)
  • [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[(2-isopropoxy-5-nitrobenzylidene)]ruthenium(II)
16   9  
Contact Us 5  

* Please contact our distributors or TCI to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.


Sold in collaboration with Apeiron Synthesis.

Product Number N1060
Purity / Analysis Method >97.0%(HPLC)
Molecular Formula / Molecular Weight C__3__1H__3__7Cl__2N__3O__3Ru = 671.63  
Physical State (20 deg.C) Solid
CAS RN 502964-52-5
Reaxys Registry Number 19324055
PubChem Substance ID 354334037
MDL Number


Appearance Green to Dark green powder to crystal
Purity(HPLC) min. 97.0 area%
Elemental analysis(Nitrogen) 5.90 to 6.50 %
Properties (reference)
Related Laws:
Transport Information:
H.S.code* 2843.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
TCI Practical Example: Olefin Metathesis Using nitro-Grela

Used Chemicals


In a 200 mL two necked round bottomed flask, nitro-Grela (15 mg, 22 µmol) was added, and purged with N2. Dichloromethane (40 mL) was charged in the flask, and diethyl diallylmalonate (237 mg, 986 µmol) in dichloromethane (5.5 mL) was added dropwise and the mixture was stirred at room temperature for 6 h. The solvent was removed under reduced pressure and the residue was purified by silica-gel column chromatography (hexane : EtOAc = 1 : 1) to give diethyl cyclopent-3-ene-1,1-dicarboxylate as a pale yellow oil (206 mg, 98%).

Experimenter's Comments

The reaction mixture was monitored by NMR.

Analytical Data(Diethyl cyclopent-3-ene-1,1-dicarboxylate)

1H NMR (400 MHz, CDCl3); δ 5.61 (s, 2H), 4.20 (q, J = 8.0 Hz, 4H), 3.01 (s, 4H), 1.25 (t, J = 8.0 Hz, 6H).

Lead Reference

Nitro-Grela: A Metathesis Catalyst Applicable to Macrocycle construction


Nitro-Grela: A Metathesis Catalyst Applicable to Various Substrates


Nitro-Grela: A Ruthenium Complex Useful for Metathesis Reactions

Experimental procedure2): A mixture of 1 (25.0 mg, 69.3 µmol) and nitro-Grela (929 µg, 1.39 µmol) in CH2Cl2 (3.5 mL) is stirred at room temperature for 2 h. The mixture is concentrated to give a residue, which is subjected to column chromatography on silica gel. Elution with hexane:ethyl acetate (10:1) gives 2 (15.6 mg, 74% yield) as a colorless oil.


Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.

The requested SDS is not available.

Please Contact Us for more information.

C of A & Other Certificates
Please enter Lot Number Incorrect Lot Number is entered
Analytical Charts
Please enter Lot Number Incorrect Lot Number is entered

The requested analytical chart is not available. Sorry for the inconvenience.

Other Documents