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CAS RN: 67719-69-1 | Product Number: C1411

Tebbe Reagent (ca. 0.5mol/L in Toluene)


Purity:
Synonyms:
  • μ-Chloro-μ-methylene[bis(cyclopentadienyl)titanium]dimethylaluminum (ca. 0.5mol/L in Toluene)
  • μ-Chlorobis(η5-cyclopentadienyl)(dimethylaluminum)-μ-methylenetitanium (ca. 0.5mol/L in Toluene)
Documents:
25ML
$219.00
18   ≥20 

* Please contact our distributors or TCI to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.


Product Number C1411
Molecular Formula / Molecular Weight C__1__3H__1__8AlClTi = 284.59  
Physical State (20 deg.C) Liquid
Storage Temperature 0-10°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive,Heat Sensitive
Packaging and Container 25ML-Vial (View image)
CAS RN 67719-69-1
Merck Index (14) 9091
MDL Number

MFCD00151575

Specifications
Appearance Dark red clear liquid to cloudy liquid
Concentration(Argentometric titration) 22.0 to 27.0 w/w%
Properties (reference)
Flash point 1 °C
GHS
Pictogram Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H312 + H332 : Harmful in contact with skin or if inhaled.
H314 : Causes severe skin burns and eye damage.
H360 : May damage fertility or the unborn child.
H370 : Causes damage to organs.
H372 : Causes damage to organs through prolonged or repeated exposure.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H304 : May be fatal if swallowed and enters airways.
H401 : Toxic to aquatic life.
H225 : Highly flammable liquid and vapor.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P273 : Avoid release to the environment.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P202 : Do not handle until all safety precautions have been read and understood.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P201 : Obtain special instructions before use.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P405 : Store locked up.
Related Laws:
Transport Information:
UN Number UN2924
Class 3 / 8
Packing Group II
H.S.code* 2931.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Methylenation Reagent

Typical Proce: To ester (224 mg, 0.85 mmol) in dry THF (2.5 mL) at 0 ℃ is added Tebbe reagent in toluene (0.5 M, 1.7mL). The mixture is allowed to warm to room temperature and, after 30 min, Et2O (10 mL) is added, followed by the slow addition of aqueous NaOH (0.1 M) while stirring the mixture. After gas evolution cease, the mixture is dried (Na2SO4) and filtered through Celite. Evaporation and chromatography give enol ether(175 mg, 79%).

Reference


Application
Ring-Closing Metathesis Using Tebbe Reagent

Reference


Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
C of A & Other Certificates
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Analytical Charts
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