Product Document Searching Made Easy by 2D Code! | TCI Chemistry News June 2026 | [TCIPracticalExample] Oxidation Reaction of Heterocycles Using... | Various analytical charts can be searched on each product detail page and Product Document Search (The kinds of analytical charts differ by product)
Maximum quantity allowed is 999
请选择数量
CAS RN: 109-63-7 | 產品號碼: B0527
Boron Trifluoride - Ethyl Ether Complex
×
* 以上價格已含運費關稅等但一些需要海運以及乾冰運輸的產品除外,詳情請與
當地經銷商
洽詢。
* TCI會時常優化儲存條件,儲存溫度請以在線目錄為準，敬請留意。
補充產品訊息:
Both 100mL and 500mL bottles of this product are attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".
| 產品號碼 | B0527 |
純度/分析方法 
|
>98.0%(W) |
| 分子式 / 分子量 | BF__3·C__4H__1__0O = 141.93 |
| 外觀與形狀（20°C） | Liquid |
| 儲存條件
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| 儲存在惰性氣體下 | Store under inert gas |
| 應避免的情況 | Air Sensitive,Moisture Sensitive |
| 包裝和容器
|
100ML-DualSeal Bottle （閲覽圖片）, 25ML-DualSeal Bottle （閲覽圖片）, 500ML-DualSeal Bottle （閲覽圖片） |
| CAS RN | 109-63-7 |
| Reaxys-RN | 3909607 |
| PubChem Substance ID | 87563549 |
| Merck Index(14) | 1350 |
| MDL編號 | MFCD00013194 |
產品規格
| Appearance | Colorless to Yellow to Orange clear liquid |
| Purity(Gravimetric) | 98.0 to 102.0 % |
| NMR | confirm to structure |
性質
| 熔點 | -60 °C |
| 沸點 | 124 °C |
| 比重 | 1.13 |
| 折射率 | 1.34 |
| 溶解性（可溶於） | Ether, Alcohol |
GHS
| 圖形表示 |
|
| 信號詞 | Danger |
| 危險性說明 | H302 + H312 : Harmful if swallowed or in contact with skin. H314 : Causes severe skin burns and eye damage. H226 : Flammable liquid and vapor. |
| 防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P270 : Do not eat, drink or smoke when using this product. P240 : Ground and bond container and receiving equipment. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 : Keep container tightly closed. P243 : Take action to prevent static discharges. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use non-sparking tools. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
相關法規
運輸資料
| UN編號 | UN2604 |
| 類別 | 8 / 3 |
| 包裝類別 | I |
| HS編碼* | 3822.19-000 |
Application
t-Bu protection of Alcohols using Isobutylene
References
- Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
- P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.
Application
Deprotection of BOM Groups using Benzenethiol and Boron Trifluoride
References
- Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
- P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.
Application
BF3·Et2O Functioning as a Fluorine Source in an PhIO mediated Intermolecular Aminofluorination
Typical Procedure: To a solution of N-(but-3-en-1-yl)-4-methylbenzenesulfonamide (45 mg, 0.2 mmol) in CH2Cl2 (6 mL) in a flask are added BF3·Et2O (28.2 mg, 0.2 mmol) and PhIO (88 mg, 0.4 mmol). The reaction is stirred at room temperature for 4 h. The resulting mixture is diluted with ethyl acetate (50 mL). Then, the mixture is washed with sat. aqueous NaHCO3 (5 mL) and Na2S2O3 (5 mL). The separated aqueous phase is extracted with EtOAc (2×10 mL). The combined organic layer is washed with brine (10 mL), dried over MgSO4 and concentrated in vacuo to afford the crude product which is purified by flash column chromatography (Rf = 0.12, petroleum ether/EtOAc = 9/1) to give 3-fluoro-1-tosylpyrrolidine as a colorless solid (39 mg, 80% yield).
References
Application
Stereoselective ring-opening hydrofluorination of aryl epoxides
Typical procedure: (RS,RS)-2-Methyl-3-phenyloxirane (4.5 g), BF3· OEt2 (1.38 mL) and CH2Cl2 (134 mL) were reacted at 20 °C for 5 min. Saturated aqueous NaHCO3 was then added and the mixture was stirred vigorously until both layers became clear. The layers were separated and the organic phase was washed with sat. aq. NaHCO3. The combined aqueous phases were extracted twice with CH2Cl2 and the combined organic extracts were dried and concentrated in vacuo. The residue was purified by flash column chromatography (gradient elution, 5 % to 40 % EtOAc in 30~40 °C petrol) gave (RS,RS)-1-fluoro-1-phenylpropane-2-ol as a colorless oil (4.31 g, 83 %, more than 99:1 dr).
References
PubMed Literature
Please visit the Pubchem page at this link.
文檔
產品介紹報導
[Product Highlights] Hypervalent Iodine-Catalyzed Balz–Schiemann Fluorination[Research Articles] BF3·Et2O Functioning as a Fluorine Source in an PhIO mediated Intermolecular Aminofluorination
[Research Articles] Stereoselective Ring-Opening Hydrofluorination of Aryl Epoxides
產品文件 （部分產品的分析圖譜無法提供，敬請諒解。）
請輸入TCI產品號碼
text.certificate.product.input.placeholder.kishida
4或5個單字節字母數字字符
text.certificate.lotno.input.placeholder.kishida
SDS
產品規格
沒有搜索到 產品規格。
如需更多幫助，請 聯繫我們 。
text.specification.search.errormsg.content.1.kishida
檢驗報告(CoA)及其他文檔
請輸入批號
輸入的批號不正確
text.certificate.analysis.pdf.lotNumber.errorMessage.alphanumeric.kishida
• 請確認您輸入的批號。
• 如果您輸入的信息無誤，請 聯繫我們 。
• text.certificate.analysis.pdf.errormsg.content6.kishida
示例 CoA
可下載CoA示例。注：該示例可能非最新批次的CoA。
目前沒有該產品的 CoA 示例。
分析圖譜
請輸入批號
輸入的批號不正確
text.certificate.analysis.pdf.lotNumber.errorMessage.alphanumeric.kishida
很抱歉，您搜索的分析圖譜無法提供。
其他文件
Related Products
Sulfur Dioxide (ca. 2.5% in Dichloromethane, ca. 0.5 mol/L)
| 產品號碼 | U0148 |
| CAS RN | 7446-09-5 |
| Purity #: |
![Hydrogen Chloride - Methanol Reagent (5-10%) [for Esterification]](/_ui/responsive/theme-tci/images/missing_product_srp.jpg "Hydrogen Chloride - Methanol Reagent (5-10%) [for Esterification]")
Hydrogen Chloride - Methanol Reagent (5-10%) [for Esterification]
| 產品號碼 | X0041 |
| CAS RN | 7647-01-0 |
| Purity #: |
Sulfur Dioxide (ca. 8% in Tetrahydrofuran, ca. 1.2 mol/L)
| 產品號碼 | U0147 |
| CAS RN | 7446-09-5 |
| Purity #: |