Maximum quantity allowed is 999
请选择数量
CAS RN: 224311-51-7 | 產品號碼: D3387
2-(Di-tert-butylphosphino)biphenyl
×
![]()
×
* 以上價格已含運費關稅等但一些需要海運以及乾冰運輸的產品除外,詳情請與
當地經銷商
洽詢。
* TCI會時常優化儲存條件,儲存溫度請以在線目錄為準，敬請留意。
補充產品訊息:
This product is intended for research and development purposes only. It may not be used for (i) any human or veterinary use, including without limitation therapeutic and prophylactic use, (ii) any clinical use, including without limitation diagnostic use. Any use of this product for any of the above mentioned purposes requires a license from the Massachusetts Institute of Technology.
List of Patent Applications and Patents (PDF)
| 產品號碼 | D3387 |
純度/分析方法 
|
>98.0%(GC) |
| 分子式 / 分子量 | C__2__0H__2__7P = 298.41 |
| 外觀與形狀（20°C） | Solid |
| 儲存條件
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| 包裝和容器
|
1G-Glass Bottle with Plastic Insert （閲覽圖片） |
| CAS RN | 224311-51-7 |
| Reaxys-RN | 8322131 |
| PubChem Substance ID | 87558786 |
| MDL編號 | MFCD01862440 |
產品規格
| Appearance | White to Almost white powder to crystal |
| Purity(GC) | min. 98.0 % |
| Melting point | 85.0 to 89.0 °C |
性質
| 熔點 | 87 °C |
| 水溶性 | Insoluble |
| 溶解性（可溶於） | Toluene |
GHS
| 圖形表示 |
|
| 信號詞 | Warning |
| 危險性說明 | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H413 : May cause long lasting harmful effects to aquatic life. |
| 防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
相關法規
運輸資料
| HS編碼* | 2931.49-900 |
Application
TCI Practical Example: Buchwald-Hartwig Amination Using JohnPhos
Used Chemicals
Procedure
-
To a solution of sodium tert-butoxide (0.54 g, 5.6 mmol), palladium(II) acetate (4.5 mg, 0.020 mmol), and JohnPhos (0.012 g, 0.040 mmol) in toluene (8 mL) 4-chlorotoluene (0.51 g, 4.0 mmol) and morpholine (0.42 g, 4.8 mmol) were successively added at room temperature. The mixture was stirred under nitrogen atmosphere at room temperature for 1.5 days, then under reflux condition for 0.5 days. Diethyl ether (20 mL) was added to the reaction mixture and filtered through celite. Solvent was removed and the residue was purified by column chromatography (1:4 ethyl acetate / hexane on SiO2), giving 4-(p-tolyl)morpholine as a pale brown solid (0.45 g, 63% yield).
Experimenter's Comments
The reaction mixture was monitored by 1H NMR.
Analytical Data (4-(p-Tolyl)morpholine)
1H NMR (400 MHz, CDCl3); δ 7.10 (d, J = 8.2 Hz, 2H), 6.85 (d, J = 8.2 Hz, 2H), 3.87 (t, J = 4.6 Hz, 4H), 3.12 (t, J = 4.8 Hz, 4H), 2.28 (s, 3H).
13C NMR (101 MHz, CDCl3); δ 129.9 (4 C), 116.2 (2 C), 67.1 (2 C), 50.1 (2 C), 20.6.
Lead Reference
- A Highly Active Catalyst for the Room-Temperature Amination and Suzuki Coupling of Aryl Chlorides
Other References
- Simple, Efficient Catalyst System for the Palladium-Catalyzed Amination of Aryl Chlorides, Bromides, and Triflates
Application
Fluorination of Alkynes using an Stable HF Complex : DMPU-HF and Gold Catalyst
Reference
- Designer HF-Based Fluorination Reagent: Highly Regioselective Synthesis of Fluoroalkenes and gem-Difluoromethylene Compounds from Alkynes
Application
Vinylation of aryl bromides
Reference
考研文獻
文檔
產品介紹報導
產品文件 （部分產品的分析圖譜無法提供，敬請諒解。）
SDS
請選擇語言。
請求的SDS不可用。
如需更多幫助，請聯繫我們 。
產品規格
檢驗報告(CoA)及其他文檔
請輸入批號
輸入的批號不正確
示例 CoA
可下載CoA示例。注：該示例可能非最新批次的CoA。
目前沒有該產品的 CoA 示例。
分析圖譜
請輸入批號
輸入的批號不正確
很抱歉，您搜索的分析圖譜無法提供。