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Published TCIMAIL newest issue No.198

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Published TCIMAIL newest issue No.198

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CAS RN: 68569-14-2 | Product Number: T3023

Tetrakis(acetonitrile)palladium(II) Bis(trifluoromethanesulfonate)

Purity: >95.0%(T)(N)

Synonyms:

Tetrakis(acetonitrile)palladium(II) Ditriflate

Product Documents:

Size	Unit Price	Belgium	Japan*	Quantity
1G	€124.00	4	13

*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).

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General Information plus

Specifications & Properties plus

Specifications

Appearance	Light yellow to Amber powder to crystal
Purity(Chelometric Titration)	min. 95.0 %
Purity(with Total Nitrogen)	min. 95.0 %
NMR	confirm to structure

Properties (reference)

Safety & Regulations plus

GHS

Pictogram
Signal Word	Warning
Hazard Statements	H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation.
Precautionary Statements	P261 : Avoid breathing dust. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.

Related Laws:

Transport Information:

HS Number

2843909000

Applications & Literature plus

Application

Catalytic Decarboxylative Cross-Coupling of Aryl Chlorides and Benzoates

T0847,T3023

Typical Procedure:
An oven-dried, nitrogen-flushed 20 mL crimp cap vessel is charged with the potassium carboxylate (0.60 mmol, 1.2 eq.), (MeCN)₄Pd(OTf)₂ (5.7 mg, 0.01 mmol, 2.0 mol%), XPhos (12.3 mg, 0.025 mmol, 5.0 mol %), copper(I) iodide (9.7 mg, 0.05 mmol, 10.0 mol%), 3,4,7,8-tetramethyl-1,10-phenanthroline (11.9 mg, 0.05 mmol, 10.0 mol%), and aryl chloride (0.5 mmol). A degassed mixture of NMP (2.5 mL) and quinoline (2.5 mL) is added via syringe. The resulting solution is then stirred at 190 °C for 16 h. After the reaction is complete, the mixture is cooled to room temperature, diluted with 1N HCl and extracted with ethyl acetate (3×50 mL). The combined organic layers are washed with water and brine, dried over MgSO₄, filtered, and concentrated in vacuo. The residue is purified by column chromatography (SiO₂, ethyl acetate/cyclohexane gradient) yielding the corresponding product.

References

J. Tang, A. Biafora, L. J. Goossen, Angew. Chem. Int. Ed. 2015, 54, 13130.

Application

Trifluoromethylthiolation via Palladium-catalyzed Directed C–H Bond Activation

Reference

Palladium-Catalyzed Trifluoromethylthiolation of Aryl C?H Bonds
- C. Xu, Q. Shen, Org. Lett. 2014, 16, 2046.

PubMed Literature

Documents

Suzuki-Miyaura Cross Coupling Reaction

Product Articles

[Research Articles] Catalytic Decarboxylative Cross-Coupling of Aryl Chlorides and Benzoates

Product Documents (Note: Some products will not have analytical charts available.)

Safety Data Sheet (SDS)

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Specifications

C of A & Other Certificates

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Analytical Charts

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Product Number	T3023
Purity / Analysis Method	>95.0%(T)(N)
Molecular Formula / Molecular Weight	C__1__0H__1__2F__6N__4O__6PdS__2 = 568.76
Physical State (20 deg.C)	Solid
Storage Temperature	Refrigerated (0-10°C)
Store Under Inert Gas	Store under inert gas
Condition to Avoid	Moisture Sensitive,Heat Sensitive
Packaging and Container	1G-Glass Bottle with Plastic Insert (View image)
CAS RN	68569-14-2
Reaxys Registry Number	17565311
PubChem Substance ID	253662101

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CAS RN: 68569-14-2 | Product Number: T3023