TCI Chemistry News
Maximum quantity allowed is 999
Please select the quantity
November 2023
TCI offers an extensive catalog of over 30,000 high quality organic reagents suitable for benchtop-to-bulk chemistry. This issue covers our chemistry topics as follows:
- Thianthrenium Salt Useful for Electrophilic Vinylation
- Safe and Easy-to-handle Trifluoromethoxylating Agent: TFNf
- Z-Stereoselective Horner-Wadsworth-Emmons Olefination via Still-Gennari Method
- Sandmeyer Reaction Using tBuONO
- Printed Magazine: TCIMAIL 194
- Product Document Searching Made Easy!
Thianthrenium Salt Useful for Electrophilic Vinylation
5-Vinylthianthrenium tetrafluoroborate [E1521] is a crystalline solid stable against air and moisture. E1521 can be used for N-vinylation of nitrogen-containing heteroaromatic compounds and for vinylation via Suzuki-Miyaura type cross-coupling reaction. In addition, it has been reported that the annulation of heterocycles proceeds by using E1521 as the C-2 unit.
Safe and Easy-to-handle Trifluoromethoxylating Agent: TFNf
TFNf [T4150] is a safe, easy-to-handle and stable liquid that functions as a practical generator of active CF3O anion species. TFNf enables trifluoromethoxylation of electrophilic substrates such as alkyl halides and triflates, unsaturated and aromatic compounds. Therefore the trifluoromethoxylation using TFNf is expected to be useful for the synthesis of biologically active compounds and drug discovery studies.
TCI Practical Example: Z-Stereoselective Horner-Wadsworth-Emmons Olefination via Still-Gennari Method
TCI introduces the Z-selective olefination of p-tolualdehyde using bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate [B1714] as a Horner-Wadsworth-Emmons reagent.
TCI Practical Example: Sandmeyer Reaction Using tBuONO
We are proud to present the preparation of diazonium salt from p-anisidine using tBuONO [N0357] and followed by the Sandmeyer reaction to introduce the iodo group.
Printed Magazine: TCIMAIL 194
Released in November 2023, TCI's latest issue features Prof. Junya Masumoto and coworkers’ article and Prof. Nagatoshi Nishiwaki’s chemistry chat. We also feature research on:
Product Document Searching Made Easy!
We began affixing a 2D code sticker to the top surface of the caps of our product containers.*Depending on the products, certain items may not contain the sticker.
When the 2D code is scanned by your mobile device, a dedicated web page will open, allowing you to check various documents for the product at hand with a single tap. The information provided will be expanded in the future.
Upcoming Events
How to Order TCI ProductsTo order, please contact your local distributor found below.» Our distributors |
| * The prices displayed in the landing website are USD based catalog prices. TCI has specific website and local currency based price list for customers in South Korea, Singapore, and Australia. For customers in other Asia Pacific countries / regions, please visit our Asia Pacific Website and contact our local distributors for the end user's cost. (The USD prices that are shown in Asia Pacific websites are TCI's catalog prices.) Please visit each country/region's website from the following links and confirm the prices. https://www.TCIchemicals.com |
|
If you are interested in our biweekly e-enewsletter "TCI News" and want to receive regularly, please click the link below and sign up. TCI News Sign-Up |
|
Tokyo Chemical Industry Co., Ltd. (TCI) Global Business Department Customer Support and Technical service » globalbusiness@TCIchemicals.com » https://www.TCIchemicals.com |