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Published TCIMAIL newest issue No.198
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Chiral Ligands
No.105(June 2001)
Chiral ligand 1 is used for enantioselective addition of Grignard reagents to ketones which affords tertiary alcohols with high optical yields1). Furthermore, a variety of titanium complexes may be prepared from 1, and the titanium complexes are used for asymmetric allylation reactions2), asymmetric alkylation reactions3), asymmetric iodocarbocyclization reactions4), and asymmetric Diels-Alder reactions5) etc.
References
- 1)Asymmetric addition of primary alkyl Grignard reagents to ketones
- 2)Asymmetric allylation of aldehydes
- 3)Asymmetric alkylation of aldehydes
- 4)Asymmetric iodocarbocyclization
- 5)Asymmetric Diels-Alder reaction
Related Compounds
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