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Published TCIMAIL newest issue No.198
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CAS RN: 1271-66-5 | Product Number: D4100
Dimethyltitanocene (5% in Tetrahydrofuran/Toluene)
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Purity:
Synonyms:
- Bis(cyclopentadienyl)dimethyltitanium (5% in Tetrahydrofuran/Toluene)
- Petasis Reagent (5% in Tetrahydrofuran/Toluene)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 25G |
€87.00
|
1 | 22 |
|
| 100G |
€274.00
|
2 | 23 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
Supplemental Product Information:
This product cannot be shipped to Russia and Turkey.
| Product Number | D4100 |
| Molecular Formula / Molecular Weight | C__1__2H__1__6Ti = 208.13 |
| Physical State (20 deg.C) | Liquid |
Storage Temperature 
|
Frozen (<0°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive,Heat Sensitive |
| CAS RN | 1271-66-5 |
| Reaxys Registry Number | 14221496 |
| PubChem Substance ID | 135727045 |
| MDL Number | MFCD02093882 |
Specifications
| Appearance | Orange to Red clear liquid |
| Concentration(HNMR) | 5.0 to 5.7 w/w% |
| NMR | confirm to structure |
Properties (reference)
| Specific Gravity (20/20) | 0.89 |
| Refractive Index | 1.49 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H332 : Harmful if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H351 : Suspected of causing cancer. H335 : May cause respiratory irritation. H361d : Suspected of damaging the unborn child. H336 : May cause drowsiness or dizziness. H304 : May be fatal if swallowed and enters airways. H225 : Highly flammable liquid and vapour. |
| Precautionary Statements | P260 : Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P201 : Obtain special instructions before use. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P331 : Do NOT induce vomiting. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. |
Related Laws:
Transport Information:
| UN Number | UN1993 |
| Class | 3 |
| Packing Group | II |
| HS Number | 3822190090 |
Application
Methylenations of Carbonyl Compounds
References
- N. A. Petasis, E. I. Bzowej, J. Am. Chem. Soc. 1990, 112, 6392.
- N. A. Petasis, S.-P. Lu, E. I. Bzowej, D.-K. Fu, J. P. Staszewski, I. Akritopoulou-Zanze, M. A. Patane, Y.-H. Hu, Pure Appl. Chem. 1996, 68, 667.
Application
Ring-Closing Metathesis Using Petasis Reagent
Reference
- Olefin Metathesis in Cyclic Ether Formation. Direct Conversion of Olefinic Esters to Cyclic Enol Ethers with Tebbe-Type Reagents
PubMed Literature
Documents
Product Articles
[TCIMAIL No.155] Short Topic: More ways to use reagents | Ring-Closing Metathesis Using Tebbe or Petasis ReagentProduct Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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