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CAS RN: 1414707-08-6 | Product Number: A3009
AquaMet
×
Purity: >95.0%(HPLC)
Synonyms:
- [1,3-Bis(2,4,6-trimethylphenyl)-4-[(4-ethyl-4-methylpiperazinium-1-yl)methyl]-2-imidazolidinylidene]dichloro(2-isopropoxybenzylidene)ruthenium(II) Chloride
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 100MG |
€228.00
|
1 | 1 |
|
|
| 500MG |
€779.00
|
1 | 5 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
Supplemental Product Information:
Sold in collaboration with Apeiron Synthesis.
PCT/EP2013/053967
| Product Number | A3009 |
Purity / Analysis Method 
|
>95.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__3__9H__5__5Cl__3N__4ORu = 803.32 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Hygroscopic,Heat Sensitive |
| Packaging and Container
|
100MG-Glass Bottle with Plastic Insert (View image), 500MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 1414707-08-6 |
| Reaxys Registry Number | 27464286 |
| PubChem Substance ID | 354334182 |
| MDL Number | MFCD28411647 |
Specifications
| Appearance | Light yellow to Amber to Dark green powder to crystal |
| Purity(HPLC) | min. 95.0 area% |
| NMR | confirm to structure |
Properties (reference)
GHS
Related Laws:
Transport Information:
| HS Number | 2843909000 |
Application
TCI Practical Example: Olefin Metathesis
Used Chemicals
- Diethyl Diallylmalonate [D1183]
- AquaMet [A3009]
- Dichloromethane
Procedure
-
In a 200 mL two necked round bottomed flask, AquaMet (50 mg, 52 μmol) was added, and purged with N2. Dichloromethane (100 mL) was charged in the flask, and diethyl diallylmalonate (500 mg, 2.08 mmol) in dichloromethane (20 mL) was added dropwise and the mixture was stirred at room temperature for 6 h. The solvent was removed under reduced pressure and the residue was purified by silica-gel column chromatography (hexane : EtOAc = 1 : 1) to give diethyl cyclopent-3-ene-1,1-dicarboxylate as a pale yellow oil (430 mg, 98%).
Experimenter's Comments
The reaction mixture was monitored by NMR.
Analytical Data（Diethyl cyclopent-3-ene-1,1-dicarboxylate）
1H NMR (400 MHz, CDCl3); δ 5.61 (s, 2H), 4.20 (q, J = 8.0 Hz, 4H), 3.01 (s, 4H), 1.25 (t, J = 8.0 Hz, 6H).
Lead Reference
- Nitro-Substituted Hoveyda−Grubbs Ruthenium Carbenes: Enhancement of Catalyst Activity through Electronic Activation
Application
Metathesis Catalyst Usable in Water Media
Flask equipped with a magnetic stirring bar is charged with Z-olefin (8.7 mg, 0.15 mmol) and non-degassed D2O (1.5 ml). Next to this solution AquaMet (0.6 mg, 0.75 µmol) is added. Reaction mixture is stirred at 25 °C for 1.1 h. Next 0.7 ml of reaction mixture is transferred to an NMR tube. Yield of a product (71%) is determined using NMR method.
References
- Highly active catalysts for olefin metathesis in water
Application
Ring Closing Metathesis in Water Media
References
- Highly active catalysts for olefin metathesis in water
Application
Mesoporous Silica Supported Metathesis Catalyst
References
- Ru-based complexes with quaternary ammonium tag immobilized on mesoporous silica as olefin metathesis catalysts
Documents
Product Articles
[Product Highlights] Metathesis Catalyst Usable in Water Media[TCI Practical Example] Olefin Metathesis with AquaMet
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