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Published TCIMAIL newest issue No.199
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CAS RN: 2613-26-5 | Product Number: N0742
3-Nitrophenylsulfur Pentafluoride
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Purity: >96.0%(GC)
Synonyms:
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
€60.00
|
3 | Contact Us |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | N0742 |
Purity / Analysis Method 
|
>96.0%(GC) |
| Molecular Formula / Molecular Weight | C__6H__4F__5NO__2S = 249.16 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 2613-26-5 |
| Reaxys Registry Number | 2699206 |
| PubChem Substance ID | 87559737 |
| MDL Number | MFCD00221621 |
Specifications
| Appearance | Light yellow to Yellow to Orange clear liquid |
| Purity(GC) | min. 96.0 % |
Properties (reference)
| Boiling Point | 83 °C/2.2 mmHg |
| Specific Gravity (20/20) | 1.68 |
| Refractive Index | 1.48 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H301 + H311 + H331 : Toxic if swallowed, in contact with skin or if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P261 : Avoid breathing mist or vapours. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. |
Related Laws:
Transport Information:
| UN Number | UN2810 |
| Class | 6.1 |
| Packing Group | III |
| HS Number | 2930909599 |
Application
Preparation of Horner-Emmons Reagents by Vicarious Nucleophilic Substitution (VNS) Reaction
Reference
- Highly selective synthesis of (E)-alkenyl-(pentafluorosulfanyl)benzenes through Horner?Wadsworth?Emmons reaction
Application
Siteselective arylations of 3-nitrophenylsulfur pentafluoride
A 25 mL Schlenk tube equipped with a magnetic stir bar is charged with (allylPdCl)2 (2.5 mol%), PCy3·HBF4 (7.5 mol%), and K2CO3 (1.8 equiv.). The reaction tube is evacuated and backfilled with N2 (4 times), then 2,2-dimethylbutyric acid (0.3 equiv.), bromobenzene (1.5 equiv.), toluene (0.8 mL) and 3-nitrophenylsulfur pentafluoride (0.5 mmol, 1.0 equiv.) are added subsequently. The sealed tube is screw capped and heated to 130 °C for 15h. The reaction vessel is then cooled to room temperature, and the reaction mixture is concentrated in vacuo directly. The resulting residue is purified with silica gel chromatography to afford 2-nitro-[1,1'-biphenyl]-4-yl sulfurpentafluoride in 79% yield.
References
- Pd-Catalyzed Direct Arylation of Nitro(pentafluorosulfanyl)benzenes with Aryl Bromides
PubMed Literature
Documents
Product Articles
[TCIMAIL No.158] Pentafluorosulfanyl Compounds[Research Articles] Arylations of nitro(pentafluorosulfanyl)benzenes using a palladium catalyst
Product Documents (Note: Some products will not have analytical charts available.)
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