text.skipToContent text.skipToNavigation

Maximum quantity allowed is 999

Please select the quantity

CAS RN: 1580548-81-7 | Product Number: A2678

1-Acetoxy-5-bromo-1,2-benziodoxol-3(1H)-one


Purity: >97.0%(T)
Synonyms:
  • ABBX
Documents:
1G
₹8,000
2   Contact Us 2  

*Upon orders receipt, Hyderabad stocks will be dispatched on the same day & Chennai stocks will be dispatched in 3-6 working days.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*Change currency to place order in USD.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.


Product Number A2678
Purity / Analysis Method >97.0%(T)
Molecular Formula / Molecular Weight C__9H__6BrIO__4 = 384.95  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
Packaging and Container 1G-Glass Bottle with Plastic Insert (View image)
CAS RN 1580548-81-7
PubChem Substance ID 253661571
Specifications
Appearance White to Light yellow powder to crystal
Purity(Iodometric Titration) min. 97.0 %
Properties (reference)
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
Application
Oxidation of alcohols to aldehydes or ketones with a new highly active trivalent iodine compound, ABBX

A2678

Typical Procedure (oxidation of 4-methylbenzyl alcohol to 4-methylbenzaldehyde): To a solution of 4-methylbenzyl alcohol (1.0 mmol, 122.1 mg) in CHCl3 (4 mL) is added ABBX (2.0 mmol, 767.7 mg). The mixture is stirred at 60 °C for 24 h. After the reaction is completed, the reaction mixture is added to aq. NaHCO3 (10 mL). The aqueous layer is extracted with CHCl3 (3 × 10 mL), and the organic layer is dried over Na2SO4. The filtrate is concentrated under reduced pressure to give 4-methylbenzaldehyde (108.0 mg, 90% yield) with 90% purity. The aqueous layer is acidified (pH ca. 2) with 1 M aq. HCl (15 mL) and the obtained mixture is filtered to afford 2-iodo-5-bromobenzoic acid (593 mg, 91%).

References


Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.

The requested SDS is not available.

Please Contact Us for more information.

Specifications
C of A & Other Certificates
Please enter Lot Number Incorrect Lot Number is entered
Analytical Charts
Please enter Lot Number Incorrect Lot Number is entered

The requested analytical chart is not available. Sorry for the inconvenience.

Other Documents