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CAS RN: 14781-45-4 | Product Number: H0554

Bis(hexafluoroacetylacetonato)copper(II) Hydrate

Purity: >95.0%(T)
  • Copper(II) Hexafluoroacetylacetonate Hydrate
  • Hexafluoroacetylacetono Copper(II) Salt Hydrate
3   ≥40 
3   ≥40 

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Product Number H0554
Purity / Analysis Method >95.0%(T)
Molecular Formula / Molecular Weight C__1__0H__2CuF__1__2O__4·xH__2O = 477.65 (as Anhydrous)
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Hygroscopic
CAS RN 14781-45-4
PubChem Substance ID 87570941
MDL Number


Appearance Green to Dark green powder to crystal
Purity(Chelometric Titration) min. 95.0 %(calcd.on anh.substance)
Water max. 10.0 %
Properties (reference)
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
Copper-catalyzed Cyclopropanation of alpha-Diazoketones to Norcaradienes

Typical procedure (entry 4): A microwave reaction vessel is charged with a solution of the diazoketone (53 mg) in CH2Cl2 (10 mL). Cu(hfacac)2 (9.5 mg) in CH2Cl2 (2 mL) is added via syringe. The vial is placed in the microwave reactor and heated to 120 °C for 1 minute (ramp from 22 °C to 120 °C requires 2 min). The solvent is removed under reduced pressure, and the residue is purified by flash chromatography (eluent: 0 to 100 % EtOAc/hexanes) to give the norcaradiene (30mg, 64 %) as a white solid.


Useful Copper Catalyst


PubMed Literature

Documents (Note: Some products will not have analytical charts available.)
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