Maintenance Notice (4:00 AM - 9:00 AM August 24, 2025): This website is scheduled to be unavailable due to maintenance. We appreciate your patience and understanding.
Product Document Searching Made Easy by 2D Code! | [TCIPracticalExample] The Synthesis of α-Aminoamide Catalyzed...
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 104439-77-2 | Product Number: H1322
1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)
×
![]()
×
Purity:
Synonyms:
- Shvo's Catalyst
Product Documents:
| Size | Unit Price | Hyderabad | Japan* | Quantity |
|---|---|---|---|---|
| 100MG |
₹7,700.00
|
7 | 10 |
|
*Upon orders receipt, Hyderabad stocks will be dispatched on the same day.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | H1322 |
| Molecular Formula / Molecular Weight | C__6__2H__4__2O__6Ru__2 = 1,085.15 |
| Physical State (20 deg.C) | Solid |
Storage Temperature 
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Moisture Sensitive |
| CAS RN | 104439-77-2 |
| PubChem Substance ID | 125308084 |
| Merck Index (14) | 8483 |
| MDL Number | MFCD03840556 |
Specifications
| Appearance | Light yellow to Brown powder to crystal |
| Elemental analysis(Carbon) | 67.0 to 71.0 % |
Properties (reference)
| Melting Point | 227 °C |
GHS
Related Laws:
Transport Information:
Application
Reviews
References
- Shvo's diruthenium complex: a robust catalyst
- Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst
Application
Anti-Markovnikov Hydration of Vinylarenes via Triple Relay Catalysis
Typical procedure (R = H): PdCl2(CH3CN)2 (10.4 mg), Shvo’s catalyst (43.6 mg), CuCl2 (10.8 mg) and 1,4-benzoquinone (43.2 mg) are weighed into a 20 mL vial under a nitrogen atmosphere, followed by the addition of i-PrOH (2 mL) and t-BuOH (4 mL). Styrene (41.7 mg) is added to the mixture followed by addition of H2O (8.1 µL). After the resulting mixture is stirred at 85 °C for 6 h, it is diluted with pentane (6 mL) and filtered through a plug of silica gel followed by flushing with ethyl acetate (6 mL). The solvent is removed under vacuum, and the residue is purified by silica gel flash chromatography to give 2-phenylethyl alcohol (41 mg, 87 % yield).
References
Application
Synthesis of Aromatic Amines under Catalytic Transfer Hydrogenation Conditions
Typical procedure (entry 1): In a pressure tube under an argon atmosphere, the Shvo’s catalyst (22 mg), p-toluidine (429 mg), and hexylamine (202 mg) are dissolved in tert-amyl alcohol (0.5 ml). The pressure tube is fitted with a polytetrafluoroethylene cap and heated at 150 °C for 24 h in an oil bath. The solvent is removed in vacuo, and the crude product is purified by column chromatography (eluent: pentane/ethyl acetate) to give N-hexyl-4-methylaniline as colorless crystals (374 mg, 98 %).
References
PubMed Literature
Documents
Product Articles
[Research Articles] Anti-Markovnikov Hydration of Vinylarenes via Triple Relay CatalysisProduct Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.