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CAS RN: 29684-56-8 | Product Number: M1279
(Methoxycarbonylsulfamoyl)triethylammonium Hydroxide Inner Salt
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Purity: >97.0%(N)
Synonyms:
- Burgess Reagent
- Methyl N-(Triethylammoniosulfonyl)carbamate
Product Documents:
| Size | Unit Price | Hyderabad | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
₹3,900.00
|
5 | 36 |
|
| 5G |
₹6,500.00
|
4 | ≥100 |
|
| 25G |
₹20,000.00
|
Contact Us | 15 |
|
*Upon orders receipt, Hyderabad stocks will be dispatched on the same day.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | M1279 |
Purity / Analysis Method 
|
>97.0%(N) |
| Molecular Formula / Molecular Weight | C__8H__1__8N__2O__4S = 238.30 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive,Heat Sensitive |
| Packaging and Container
|
1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 29684-56-8 |
| Reaxys Registry Number | 1432131 |
| PubChem Substance ID | 87573236 |
| Merck Index (14) | 1502 |
| MDL Number | MFCD00077815 |
Specifications
| Appearance | White to Light yellow to Light orange powder to crystal |
| Purity(with Total Nitrogen) | min. 97.0 % |
| Melting point | 74.0 to 80.0 °C |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 79 °C |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
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Transport Information:
Application
Preparation of Oxazoline Derivatives Using Burgess Reagent
Typical Procedure:
A solution of dipeptide 1 (56.4 mg, 0.16 mmol) in dry THF (3 mL) is added in a Pyrex tube and flushed with nitrogen. To this solution, Burgess reagent (41.9 mg, 0.176 mmol) is added in small portions and then, the mixture is heated at 70 °C for 0.7-2.5 h until the reaction is completed. After cooling to room temperature, the mixture is evaporated onto silica gel. The resultant residue is purified by column chromatography to give the desired oxazoline derivative 2 (39.6 mg, 74% yield).
A solution of dipeptide 1 (56.4 mg, 0.16 mmol) in dry THF (3 mL) is added in a Pyrex tube and flushed with nitrogen. To this solution, Burgess reagent (41.9 mg, 0.176 mmol) is added in small portions and then, the mixture is heated at 70 °C for 0.7-2.5 h until the reaction is completed. After cooling to room temperature, the mixture is evaporated onto silica gel. The resultant residue is purified by column chromatography to give the desired oxazoline derivative 2 (39.6 mg, 74% yield).
References
Application
Burgess Dehydration Reaction
Typical Procedure:
Burgess reagent (1.3 g, 5.5 mmol) is added to a solution of alcohol 1 (.6 g, 1.8 mmol) in anhydrous THF (4 mL) under N2 atmosphere, and the resulting solution is refluxed for 1 h. The mixture is poured into H2O, then extracted with AcOEt. The organic layer is washed with brine, dried over Na2SO4, and concentrated in vacuo. The residue is purified by SiO2 column chromatography (hexane : AcOEt = 1 : 1) to give the dehydrated product 2 in quantitive yield.
Refereces
- Enantioselective Total Synthesis of a Potent Antitumor Antibiotic, Fredericamycin A.
PubMed Literature
Documents
Product Articles
[TCIMAIL No.160] Organic Syntheses Utilizing the Chemical Properties of Chlorosulfonyl Isocyanate[TCIMAIL No.097] Burgess Reagent
Product Documents (Note: Some products will not have analytical charts available.)
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Specifications
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