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CAS RN: 527-21-9 | Product Number: T0790


Purity: >98.0%(T)(HPLC)
  • Fluoranil
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Product Number T0790
Purity / Analysis Method >98.0%(T)(HPLC)
Molecular Formula / Molecular Weight C__6F__4O__2 = 180.06  
Physical State (20 deg.C) Solid
CAS RN 527-21-9
Reaxys Registry Number 1875039
PubChem Substance ID 87576632
SDBS (AIST Spectral DB) 5440
MDL Number


Appearance Light yellow to Brown powder to crystal
Purity(HPLC) min. 98.0 area%
Purity(Iodometric Titration) min. 98.0 %
Properties (reference)
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
Transport Information:
Mukaiyama Oxidation-Reduction Condensation


[Experimental procedure]
to a mixture of alkoxydiphenylphosphine (2, 0.60 mmol), prepared from the alcohol (1), n-BuLi and chlorodiphenylphosphine, and tetrafluoro-1,4-benzoquinone (0.72 mmol) under argon atmosphere is added a dichloromethane (0.50 mL) solution of alcohol (3, 0.72 mmol) at room temperature. After the reaction that is monitored by TLC was completed, the reaction mixture is quenched by adding water and the aqueous layer is extracted with dichloromethane. The organic layers are dried over anhydrous sodium sulfate. After filtration and evaporation, the resulted residue is purified by preparative TLC to afford the corresponding ether (4).


PubMed Literature

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