Maximum quantity allowed is 999
Methylene-bridged [6]cycloparaphenylene (= CPP) (1), in which each benzene ring is tethered to its neighbor rings by methylene units, is the first methylene-bridged CPP synthesized by Itami et al.1) This skeleton is the substructure of Haeckelite nanotube and C80 (Figure 1). 1 has narrower bandgap than [6]CPP by the enhancement of π-conjugation by methylene bridges. In addition, 1 forms a supramolecular structure by incorporation of small molecules into the cyclic skeleton. Furthermore, the methylene groups of this product can be selectively functionalized2) (Figure 2) and further derivatization or extension of skeleton of 1 could be expected.
![メチレン架橋[6]CPP](https://www.tcichemicals.com/assets/cms-images/TCIMAIL_190-11_01.png)
Figure 1. Substructures of Haeckelite nanotube, C80 and 1
![メチレン架橋[6]CPP](https://www.tcichemicals.com/assets/cms-images/TCIMAIL_190-11_02.png)
Figure 2. Selective functionalization of methylene moieties of 1
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